Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters | |
Ma, Yangyang1,2; Ma, Jiping1; Xia, Fei1; Lu, Fang1; Du, Zhongtian1; Xu, Jie1 | |
刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
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2019-07-10 | |
页码 | 7 |
关键词 | oxidation oxygen molybdenum mono-aromatics acid esters |
ISSN号 | 2193-5807 |
DOI | 10.1002/ajoc.201900310 |
通讯作者 | Ma, Jiping(majiping@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn) |
英文摘要 | Conversion of non-edible lignocellulosic biomass into value-added chemicals is of great significance and also particularly attractive. However, owing to the complexity and inertness, valorization of native lignocellulose remains to be quite challenging. Herein, catalytic oxidative cleavage of raw poplar sawdust was studied, mono-aromatics and organic acid esters with 34.8 wt% and 27.4 wt% yield respectively were achieved over MoO2(acac)(2) with molecular oxygen, which was suggested to be attributed to a prior cleavage of the carbohydrate fractions. This catalytic oxidation approach demonstrates the feasibility of transformation of raw woody biomass into valuable chemicals. |
资助项目 | National Natural Science Foundation of China[21790331] ; National Natural Science Foundation of China[21473184] ; National Natural Science Foundation of China[30900326] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21030400] ; Youth Innovation Promotion Association, CAS[2018219] ; DICP[ZZBS201811] |
WOS关键词 | LIGNOCELLULOSIC BIOMASS ; WOODY BIOMASS ; FORMIC-ACID ; LIGNIN ; CONVERSION ; CHEMICALS ; DEPOLYMERIZATION ; CELLULOSE ; NICKEL ; HYDROGENOLYSIS |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000477467000001 |
资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/173878] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Ma, Jiping; Xu, Jie |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Henan Agr Univ, Coll Food Sci & Technol, Zhengzhou 450002, Henan, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Yangyang,Ma, Jiping,Xia, Fei,et al. Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2019:7. |
APA | Ma, Yangyang,Ma, Jiping,Xia, Fei,Lu, Fang,Du, Zhongtian,&Xu, Jie.(2019).Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters.ASIAN JOURNAL OF ORGANIC CHEMISTRY,7. |
MLA | Ma, Yangyang,et al."Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters".ASIAN JOURNAL OF ORGANIC CHEMISTRY (2019):7. |
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