Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters

doi:10.1002/ajoc.201900310

	Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters
	Ma, Yangyang 1,2; Ma, Jiping 1; Xia, Fei 1; Lu, Fang 1; Du, Zhongtian 1; Xu, Jie 1
刊名	ASIAN JOURNAL OF ORGANIC CHEMISTRY
	2019-07-10
页码	7
关键词	oxidation oxygen molybdenum mono-aromatics acid esters
ISSN号	2193-5807
DOI	10.1002/ajoc.201900310
通讯作者	Ma, Jiping(majiping@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
英文摘要	Conversion of non-edible lignocellulosic biomass into value-added chemicals is of great significance and also particularly attractive. However, owing to the complexity and inertness, valorization of native lignocellulose remains to be quite challenging. Herein, catalytic oxidative cleavage of raw poplar sawdust was studied, mono-aromatics and organic acid esters with 34.8 wt% and 27.4 wt% yield respectively were achieved over MoO2(acac)(2) with molecular oxygen, which was suggested to be attributed to a prior cleavage of the carbohydrate fractions. This catalytic oxidation approach demonstrates the feasibility of transformation of raw woody biomass into valuable chemicals.
资助项目	National Natural Science Foundation of China[21790331] ; National Natural Science Foundation of China[21473184] ; National Natural Science Foundation of China[30900326] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21030400] ; Youth Innovation Promotion Association, CAS[2018219] ; DICP[ZZBS201811]
WOS关键词	LIGNOCELLULOSIC BIOMASS ; WOODY BIOMASS ; FORMIC-ACID ; LIGNIN ; CONVERSION ; CHEMICALS ; DEPOLYMERIZATION ; CELLULOSE ; NICKEL ; HYDROGENOLYSIS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000477467000001
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association, CAS ; Youth Innovation Promotion Association, CAS ; DICP ; DICP
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173878]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Ma, Jiping; Xu, Jie
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Henan Agr Univ, Coll Food Sci & Technol, Zhengzhou 450002, Henan, Peoples R China
推荐引用方式 GB/T 7714	Ma, Yangyang,Ma, Jiping,Xia, Fei,et al. Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2019:7.
APA	Ma, Yangyang,Ma, Jiping,Xia, Fei,Lu, Fang,Du, Zhongtian,&Xu, Jie.(2019).Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters.ASIAN JOURNAL OF ORGANIC CHEMISTRY,7.
MLA	Ma, Yangyang,et al."Molybdenum-Catalyzed Oxidative Cleavage of Raw Poplar Sawdust into Mono-Aromatics and Organic Acid Esters".ASIAN JOURNAL OF ORGANIC CHEMISTRY (2019):7.