Catalytic Synthesis of 2,5-Furandicarboxylic Acid from Concentrated 2,5-Diformylfuran Mediated by N-hydroxyimides under Mild Conditions

doi:10.1002/asia.20190100110.1002/asia.201901001

	Catalytic Synthesis of 2,5-Furandicarboxylic Acid from Concentrated 2,5-Diformylfuran Mediated by N-hydroxyimides under Mild Conditions
	Xia, Fei 1,2; Ma, Jiping 2; Jia, Xiuquan 2; Guo, Meiling ; Liu, Xuebin ; Ma, Hong 2; Gao, Jin 2,3; Xu, Jie 2,3
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2019-10-01
卷号	14 期号:19 页码:3329-3334
关键词	Aldehyde Biomass Carboxylic acid Catalytic oxidation N-Hydroxyimides
ISSN号	1861-4728
DOI	10.1002/asia.20190100110.1002/asia.201901001
通讯作者	Ma, Jiping(majiping@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
英文摘要	Producing polyester monomer 2,5-furandicarboxylic acid (FDCA) from biomass as an alternative to fossil-derived terephthalic acid has drawn much attention from both academy and industry. In this work, an efficient FDCA synthesis was proposed from 10.6 wt % 2,5-diformylfuran (DFF) in acetic acid using a combined catalytic system of Co/Mn acetate and N-hydroxyimides. The intermediate product of 5-formyl-2-furandicarboxylic acid (FFCA) possesses the least reactive formyl group. N-hydroxysuccinimide was found to be superior to N-hydroxyphthalimide in catalyzing the oxidation of the formyl group in FFCA intermediate, affording a near 95 % yield of FDCA under mild conditions of 100 degrees C. Trace maleic anhydride was detected as by-product, which mainly came from the oxidative cleavage of DFF via furfural, furoic acid and 5-acetoxyl-2(5H)-furanone as intermediates.
资助项目	National Natural Science Foundation of China[21790331] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020300] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21030400] ; Youth Innovation Promotion Association ; Chinese Academy of Sciences[2018219] ; DICP[ZZBS201811]
WOS关键词	EFFICIENT AEROBIC OXIDATION ; SELECTIVE OXIDATION ; P-XYLENE ; TEREPHTHALIC ACID ; ORGANIC-COMPOUNDS ; HIGHLY EFFICIENT ; MOLECULAR-OXYGEN ; BIOMASS ; CONVERSION ; HYDROXYPHTHALIMIDE
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000488342400017
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/172586]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Ma, Jiping; Xu, Jie
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Dalian Inst Chem Phys, Energy Innovat Lab, BP Off, Dalian 776023, Peoples R China
推荐引用方式 GB/T 7714	Xia, Fei,Ma, Jiping,Jia, Xiuquan,et al. Catalytic Synthesis of 2,5-Furandicarboxylic Acid from Concentrated 2,5-Diformylfuran Mediated by N-hydroxyimides under Mild Conditions[J]. CHEMISTRY-AN ASIAN JOURNAL,2019,14(19):3329-3334.
APA	Xia, Fei.,Ma, Jiping.,Jia, Xiuquan.,Guo, Meiling.,Liu, Xuebin.,...&Xu, Jie.(2019).Catalytic Synthesis of 2,5-Furandicarboxylic Acid from Concentrated 2,5-Diformylfuran Mediated by N-hydroxyimides under Mild Conditions.CHEMISTRY-AN ASIAN JOURNAL,14(19),3329-3334.
MLA	Xia, Fei,et al."Catalytic Synthesis of 2,5-Furandicarboxylic Acid from Concentrated 2,5-Diformylfuran Mediated by N-hydroxyimides under Mild Conditions".CHEMISTRY-AN ASIAN JOURNAL 14.19(2019):3329-3334.