Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups

doi:10.7503/cjcu20180831

	Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups
	Sheng Bingchen 1; Li Cong 1; Liu Yingya 1; Wang Anjie 1; Wang Yao 1; Zhang Jian 2; Liu Weixu 1
刊名	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
	2019-07-10
卷号	40 期号:7 页码:1365-1373
关键词	Metal-organic framework UiO-66 Nanomaterial Microfluidic synthesis
ISSN号	0251-0790
DOI	10.7503/cjcu20180831
通讯作者	Wang Yao(wangyao@dlut.edu.cn)
英文摘要	Zirconium based metal-organic framework UiO-66 was synthesized continuously by microfluidic method. Compared with the traditional solvothermal synthesis in batch reactors, microfluidic synthesis is more efficient. It has the advantages in highly efficient mixing and heat transfer, thus lead to enhanced reaction rates. Microfluidic synthesis can obtain uniform hexahedral crystalline products in nanometer range(less than 100 nm). The influences of temperature, total flowrate and residence time on the obtained products were investigated. Higher temperature benefited the growth of crystal. When flowrate increased, crystal sizes of UiO-66 synthesized by microfluidic method decreased. Crystal growth required sufficient residence time (20 min), but if the residence time was prolonged further, the crystal particle size would not change any more. By optimizing the synthetic parameters, UiO-66 modified with different functional groups, UiO-66-X (X = NH2, NO2, Br), could be synthesized continuously by microfluidic synthesis.
资助项目	National Key R&D Program of China[2016YFE0109800] ; National Natural Science Foundation of China[21473017] ; National Natural Science Foundation of China[21373215] ; Fundamental Research Funds for the Central Universities, China[DUT17JC20] ; Open Project of the State Key Laboratory of Fine Chemicals, China[KF1405]
WOS关键词	SIZE ; DESIGN ; FLOW
WOS研究方向	Chemistry
语种	英语
出版者	HIGHER EDUCATION PRESS
WOS记录号	WOS:000490720100005
资助机构	National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/172394]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang Yao
作者单位	1.Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Lab Catalysts & New Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Sheng Bingchen,Li Cong,Liu Yingya,et al. Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2019,40(7):1365-1373.
APA	Sheng Bingchen.,Li Cong.,Liu Yingya.,Wang Anjie.,Wang Yao.,...&Liu Weixu.(2019).Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,40(7),1365-1373.
MLA	Sheng Bingchen,et al."Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 40.7(2019):1365-1373.