highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides | |
Wang Wei2; Xie Yan2; Zhang Shaohua2; Liu Xing2; Zhang Liyun1; Zhang Bingsen1; Harut Masatake2; Huang Jiahui2 | |
刊名 | chinesejournalofcatalysis
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2019-01-01 | |
卷号 | 40期号:12页码:1924 |
ISSN号 | 1872-2067 |
英文摘要 | The design and preparation of suitable supports are of great importance for gold catalysts to attain excellent catalytic performance for alcohol oxidation. In this work, we found that ZnO-CuO mixed oxides supported gold catalysts showed much better catalytic activity for base-free aerobic oxidation of benzyl alcohol than Au 0.7 Cu 0.3 O displayed the best catalytic performance. In addition, the Au 0.7 Cu 0.3 O catalyst could selectively catalyze the aerobic oxidation of a wide range of alcohols to produce the corresponding carbonyl compounds with high yields under mild conditions without base. Further characterizations indicated that the outstanding catalytic performance of Au 0.7 Cu 0.3 O was correlated with the small size of Au nanoparticles (NPs), good low-temperature reducibility, high concentration of surface oxygen species, and collaborative interaction between Au NPs and mixed oxide. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/172234] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.中国科学院金属研究所 2.中国科学院大连化学物理研究所 |
推荐引用方式 GB/T 7714 | Wang Wei,Xie Yan,Zhang Shaohua,et al. highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides[J]. chinesejournalofcatalysis,2019,40(12):1924. |
APA | Wang Wei.,Xie Yan.,Zhang Shaohua.,Liu Xing.,Zhang Liyun.,...&Huang Jiahui.(2019).highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides.chinesejournalofcatalysis,40(12),1924. |
MLA | Wang Wei,et al."highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides".chinesejournalofcatalysis 40.12(2019):1924. |
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