Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions

	Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions
	Chen, Guihua ; Gui, Jiangyang ; Cao, Peng ; Liao, Jian
刊名	TETRAHEDRON
	2012
卷号	68 期号:15 页码:3220-3224
关键词	Sulfoxide-olefin 1 Rh-catalyzed 4-Addition Stereoselectivity reversal
ISSN号	0040-4020
通讯作者	Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China.
产权排序	2
英文摘要	A class of chiral sulfoxide-olefins were designed and synthesized through concise routes. Their applications as ligands in Hayashi-Miyaura reaction were studied, which found that vinyl substituents of the ligands vary in stereocontrolling ability. Particularly, either isomer of adducts with excellent ees could be readily obtained through changing the position of the substituents of olefins as well as changing the configuration of the C=C bond of the ligands. Meanwhile, the substrate scope of arylboronic acids and alkenes was clearly shown. (C) 2012 Elsevier Ltd. All rights reserved.
学科主题	Chemistry
收录类别	SCI
资助信息	NSFC [21072186, 20872139]; West Light Foundation of CAS; Chengdu Institute of Biology of CAS [Y0B1051100]; Major State Basic Research Development Program (973 program) [2010CB833300]
语种	英语
WOS记录号	WOS:000302593200011
公开日期	2013-07-03
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/23901]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Chen, Guihua,Gui, Jiangyang,Cao, Peng,et al. Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions[J]. TETRAHEDRON,2012,68(15):3220-3224.
APA	Chen, Guihua,Gui, Jiangyang,Cao, Peng,&Liao, Jian.(2012).Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions.TETRAHEDRON,68(15),3220-3224.
MLA	Chen, Guihua,et al."Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions".TETRAHEDRON 68.15(2012):3220-3224.