Rh(I)-catalyzed asymmetric addition of arylboronic acids to NH isatins

	Rh(I)-catalyzed asymmetric addition of arylboronic acids to NH isatins
	Gui, Jiangyang ; Chen, Guihua ; Cao, Peng ; Liao, Jian
刊名	TETRAHEDRON-ASYMMETRY
	2012
卷号	23 期号:8 页码:554-563
ISSN号	0957-4166
通讯作者	Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China.
产权排序	2
英文摘要	The transition metal-catalyzed asymmetric variant of the title reaction is normally limited to N-protected isatins. However, Rh(I)/chiral sulfoxide phosphine complexes were found to catalyze the enantioselective addition of arylboronic acids to NH isatins under mild conditions. A variety of chiral 3-aryl-3-hydroxyl-2-oxindoles were obtained with high yields and with good to excellent enantioselectivities (85-92% ee). (C) 2012 Elsevier Ltd. All rights reserved.
学科主题	Chemistry
收录类别	SCI
资助信息	NSFC [21072186, 20872139]; West Light Foundation of CAS, Chengdu Institute of Biology of CAS [Y0B1051100]; Major State Basic Research Development Program (973 program) [2010CB833300]
语种	英语
WOS记录号	WOS:000306304200004
公开日期	2013-07-03
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/23900]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Gui, Jiangyang,Chen, Guihua,Cao, Peng,et al. Rh(I)-catalyzed asymmetric addition of arylboronic acids to NH isatins[J]. TETRAHEDRON-ASYMMETRY,2012,23(8):554-563.
APA	Gui, Jiangyang,Chen, Guihua,Cao, Peng,&Liao, Jian.(2012).Rh(I)-catalyzed asymmetric addition of arylboronic acids to NH isatins.TETRAHEDRON-ASYMMETRY,23(8),554-563.
MLA	Gui, Jiangyang,et al."Rh(I)-catalyzed asymmetric addition of arylboronic acids to NH isatins".TETRAHEDRON-ASYMMETRY 23.8(2012):554-563.