Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones

	Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones
	Chen, Guihua ; Xing, Junwei ; Cao, Peng ; Liao, Jian
刊名	TETRAHEDRON
	2012
卷号	68 期号:29 页码:5908-5911
关键词	Chiral sulfinylphosphine 1 Chalcones 4-Addition
ISSN号	0040-4020
通讯作者	Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China.
产权排序	2
英文摘要	A general method to obtain enantioenriched 1,3,3-triarylpropan-1-ones bearing a diarylmethine stereocenter was developed using Rh/chiral sulfinylphosphine catalyzed 1,4-addition of arylboronic acids to chalcones. The catalysis progressed smoothly in the presence of 2 mol % catalyst formed in situ from [Rh(C2H4)(2)Cl](2) and chiral tert-butanesulfinylphosphine and gave the adducts with up to 99% yield and 98% ee. (C) 2012 Elsevier Ltd. All rights reserved.
学科主题	Chemistry
收录类别	SCI
资助信息	NSFC [21072186, 20872139]; West Light Foundation of CAS; Chengdu Institute of Biology of CAS [Y0B1051100]; Major State Basic Research Development Program (973 program) [2010CB833300]
语种	英语
WOS记录号	WOS:000305855800027
公开日期	2013-07-03
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/23886]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Chen, Guihua,Xing, Junwei,Cao, Peng,et al. Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones[J]. TETRAHEDRON,2012,68(29):5908-5911.
APA	Chen, Guihua,Xing, Junwei,Cao, Peng,&Liao, Jian.(2012).Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones.TETRAHEDRON,68(29),5908-5911.
MLA	Chen, Guihua,et al."Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones".TETRAHEDRON 68.29(2012):5908-5911.