Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene

	Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene
	Zheng J ; Liu F ; Lin YC ; Zhang ZJ ; Zhang GC ; Wang L ; Liu Y ; Tang T
刊名	macromolecules
	2012
卷号	45 期号:3 页码:1190-1197
关键词	LIVING ANIONIC-POLYMERIZATION CHEMICAL-MODIFICATION BLOCK-COPOLYMERS RADICAL-ADDITION POLYBUTADIENES POLYPROPYLENE SUBSTITUTION DERIVATIVES COMPLEXES
ISSN号	0024-9297
通讯作者	tang t
中文摘要	for the first time, hydrozirconation and halogenolysis of 1,2-polybutadiene (1,2-pbd, by living anionic polymerization) were studied to synthesize reactive poly-halohydrocarbons, which provide a platform for preparing well-defined functional polymers via macromolecular substitution. hrirozirconation and halogenolysis afforded quite convenience for anti-markovnikov hydrohalogenation of 1,2-pbd with controllable degree of functionalization. diverse functional polymers and branched polymers were synthesized after macromolecular substitution reaction with a broad range of commercially available nucleophiles (amines, phenols, alcohols, carbanions, carboxylates, and azide) or macromolecular nucleophiles. nmr and gpc characterizations confirmed high conversion in substitution reaction and narrow molecular weight distribution of the resultant functional polymers, respectively. the methodology utilizing schwartz's reagent for hydrozirconation of macromolecules could greatly facilitate the modification of vinyl groups containing polymers with high efficiency.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000300124200007
公开日期	2013-06-08
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48330]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Zheng J,Liu F,Lin YC,et al. Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene[J]. macromolecules,2012,45(3):1190-1197.
APA	Zheng J.,Liu F.,Lin YC.,Zhang ZJ.,Zhang GC.,...&Tang T.(2012).Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene.macromolecules,45(3),1190-1197.
MLA	Zheng J,et al."Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene".macromolecules 45.3(2012):1190-1197.