Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus

	Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus
	Zhang Q ; Zhang SB ; Li SH
刊名	macromolecules
	2012
卷号	45 期号:7 页码:2981-2988
关键词	HIGH-SURFACE-AREA INTRINSIC MICROPOROSITY PIMS HETEROGENEOUS CATALYSIS THIN-FILMS POLYMERS FRAMEWORKS POROSITY GAS PHTHALOCYANINE NANOPARTICLES
ISSN号	0024-9297
通讯作者	zhang sb
中文摘要	a quaternary phosphonium and tertiary phosphorus functionalized microporous polymer was obtained via nickel(0)-catalyzed yamamoto-type cross-coupling reaction. the integration ratio of signals (quaternary phosphonium to tertiary phosphorus atoms) was close to 3:2. the polymer networks were stable toward water, base, and acid, and indeed no change in surface area was observed even after the material was treated with 10 m hcl. the pore size distribution calculated by the horvath-kawazoe method indicated the presence of micropores with a mean width of about 0.7 and 1.4 nm. their apparent bet specific surface areas can be tuned (from 650 to 980 m(2) g(-1)) by changing the counteranions (br- to f-). it displays high intrinsic catalytic activity for the reaction between epoxide and co2 (yield: 98%, 1 atm). pd nanopartides supported on the polymer networks were also prepared, which exhibits high catalytic activity for cross-coupling reaction between 1-chlorobenzene and phenylboronic acid (yield: >95.8%).
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000302511500005
公开日期	2013-05-22
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48231]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Zhang Q,Zhang SB,Li SH. Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus[J]. macromolecules,2012,45(7):2981-2988.
APA	Zhang Q,Zhang SB,&Li SH.(2012).Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus.macromolecules,45(7),2981-2988.
MLA	Zhang Q,et al."Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus".macromolecules 45.7(2012):2981-2988.