K-3[TbxEu1-xGe3O8(OH)(2)] (x=1, 0.88, 0.67, 0): 2D-Layered Lanthanide Gerrnanates with Tunable Photo luminescent Properties

	K-3[TbxEu1-xGe3O8(OH)(2)] (x=1, 0.88, 0.67, 0): 2D-Layered Lanthanide Gerrnanates with Tunable Photo luminescent Properties
	Wang X ; Wang Y ; Liu Q ; Li Y ; Yu JH ; Xu RR
刊名	inorganic chemistry
	2012
卷号	51 期号:8 页码:4779-4783
关键词	FRAMEWORK CERIUM SILICATE CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS ENERGY-TRANSFER STRUCTURAL-CHARACTERIZATION MICROPOROUS YTTRIUM HIGH-TEMPERATURE FLUX SYNTHESIS EU TB
ISSN号	0020-1669
通讯作者	yu jh
中文摘要	a family of novel 2d-layered lanthanide germanates k-3[tbxeu1-xge3o8(oh)(2)] (x = 1, 0.88, 0.67, 0; denoted as tbgeo-ju-87, tb0.88eu0.12geo-ju-87, tb0.62eu0.33geo-ju-87, and eugeo-ju-87) were synthesized under mild hydrothermal conditions in a concentrated gel system. they are isostructural, as confirmed by the powder x-ray diffraction analysis. the single-crystal x-ray diffraction analysis of eugeo-ju-87 reveals that it is a 2d-layered [euge3o8(oh)(2)](n)(3n-) anionic framework, which is built up from geo4h/geo4 tetrahedra and euo6 octahedra by sharing vertex o atoms. charge neutrality is achieved by k+ ions located in the free void space. interestingly, photoluminescence studies show that tb0.88eu0.12geo-ju-87 and tb0.67eu0.33geo-ju-87 exhibit a high tb3+-to-eu3+ energy-transfer efficiency and the tbxeu1-xgeo-ju-87 system displays tunable photoluminescent properties.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000302833700046
公开日期	2013-05-22
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48219]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wang X,Wang Y,Liu Q,et al. K-3[TbxEu1-xGe3O8(OH)(2)] (x=1, 0.88, 0.67, 0): 2D-Layered Lanthanide Gerrnanates with Tunable Photo luminescent Properties[J]. inorganic chemistry,2012,51(8):4779-4783.
APA	Wang X,Wang Y,Liu Q,Li Y,Yu JH,&Xu RR.(2012).K-3[TbxEu1-xGe3O8(OH)(2)] (x=1, 0.88, 0.67, 0): 2D-Layered Lanthanide Gerrnanates with Tunable Photo luminescent Properties.inorganic chemistry,51(8),4779-4783.
MLA	Wang X,et al."K-3[TbxEu1-xGe3O8(OH)(2)] (x=1, 0.88, 0.67, 0): 2D-Layered Lanthanide Gerrnanates with Tunable Photo luminescent Properties".inorganic chemistry 51.8(2012):4779-4783.