Full-color emission from In2S3 and ln(2)S(3): Eu3+ nanoparticles
Chen W ; Bovin JO ; Joly AG ; Wang SP ; Su FH ; Li GH
刊名journal of physical chemistry b
2004
卷号108期号:32页码:11927-11934
关键词CUINS2 THIN-FILMS
ISSN号1520-6106
通讯作者chen, w, nomad inc, 1024 s innovat way, stillwater, ok 74074 usa. 电子邮箱地址: wchen@nomadics.com
中文摘要new observations on the luminescence of in2s3 and europium-doped in2s3 nanoparticles show a green (5 10 nm) emission from in2s3 and in1.8eu0.2s3 nanoparticles while a blue (425 nm) emission is observed from ln(1.6)eu(0.4)s(3) nanoparticles. both the blue and green emissions have large stokes shifts of 62 and 110 nm, respectively. excitation with longer-wavelength photons causes the blue emission to shift to a longer wavelength while the green emission wavelength remains unchanged. the lifetimes of both the green and blue emissions are similar to reported values for excitonic recombination. when doped with eu3+, in addition to the broad blue and green emissions, a red emission near 615 nm attributed to eu3+ is observed. temperature dependences on nanoparticle thin films indicate that with increasing temperature, the green emission wavelength remains constant, however, the blue emission shifts toward longer wavelengths. based on these observations, the blue emission is attributed to exciton recombination and the green emission to indium interstitial defects. these nanoparticles show full-color emission with high efficiency, fast lifetime decays, and good stability; they are also relatively simple to prepare, thus making them a new type of phosphor with potential applications in lighting, flat-panel displays, and communications.
学科主题半导体物理
收录类别SCI
语种英语
公开日期2010-03-09
内容类型期刊论文
源URL[http://ir.semi.ac.cn/handle/172111/7992]  
专题半导体研究所_中国科学院半导体研究所(2009年前)
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GB/T 7714
Chen W,Bovin JO,Joly AG,et al. Full-color emission from In2S3 and ln(2)S(3): Eu3+ nanoparticles[J]. journal of physical chemistry b,2004,108(32):11927-11934.
APA Chen W,Bovin JO,Joly AG,Wang SP,Su FH,&Li GH.(2004).Full-color emission from In2S3 and ln(2)S(3): Eu3+ nanoparticles.journal of physical chemistry b,108(32),11927-11934.
MLA Chen W,et al."Full-color emission from In2S3 and ln(2)S(3): Eu3+ nanoparticles".journal of physical chemistry b 108.32(2004):11927-11934.
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