Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes | |
Cui P(崔鹏) ; Chen YF(陈耀峰) ; Zhang Q(张强) ; Li GY(李光玉) ; Xia W(夏薇) | |
刊名 | J. Organomet. Chem.
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2010 | |
卷号 | 695期号:25-26页码:2713-2719 |
ISSN号 | 0022-328X |
其他题名 | 无溶剂配位的双硼杂苯和环戊二烯基硼杂苯基二价镱化合物的合成和结构 |
通讯作者 | 陈耀峰 |
英文摘要 | The preparation and characterization of the solvent-free divalent ytterbium bis(boratabenzene) complex [C5H5BCH2(CH3)(2)P -> BC5H5](2)Yb (2a) and heteroleptic complexes [(C5H3RR2)-R-1][C5H5BCH2(CH3)(2)P -> BC5H5] Yb (3: R-1 = SiMe3, R-2 = H; 4: R-1 = R-2 = SiMe3) are reported. The interactions between the pendant neutral borabenzene and the ytterbium center were observed both in the solid-state and in benzene. Addition of external sigma-donor solvent THF to the complexes caused a dissociation of the neutral borabenzene from the ytterbium center. (c) 2010 Elsevier B.V. All rights reserved. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.jorganchem.2010.09.001 |
语种 | 英语 |
WOS记录号 | WOS:000284470900004 |
公开日期 | 2013-04-11 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/25333] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Cui P,Chen YF,Zhang Q,et al. Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes[J]. J. Organomet. Chem.,2010,695(25-26):2713-2719. |
APA | 崔鹏,陈耀峰,张强,李光玉,&夏薇.(2010).Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes.J. Organomet. Chem.,695(25-26),2713-2719. |
MLA | 崔鹏,et al."Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes".J. Organomet. Chem. 695.25-26(2010):2713-2719. |
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