Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes

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	Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes
	Cui P(崔鹏) ; Chen YF(陈耀峰) ; Zhang Q(张强) ; Li GY(李光玉) ; Xia W(夏薇)
刊名	J. Organomet. Chem.
	2010
卷号	695 期号:25-26 页码:2713-2719
ISSN号	0022-328X
其他题名	无溶剂配位的双硼杂苯和环戊二烯基硼杂苯基二价镱化合物的合成和结构
通讯作者	陈耀峰
英文摘要	The preparation and characterization of the solvent-free divalent ytterbium bis(boratabenzene) complex [C5H5BCH2(CH3)(2)P -> BC5H5](2)Yb (2a) and heteroleptic complexes [(C5H3RR2)-R-1][C5H5BCH2(CH3)(2)P -> BC5H5] Yb (3: R-1 = SiMe3, R-2 = H; 4: R-1 = R-2 = SiMe3) are reported. The interactions between the pendant neutral borabenzene and the ytterbium center were observed both in the solid-state and in benzene. Addition of external sigma-donor solvent THF to the complexes caused a dissociation of the neutral borabenzene from the ytterbium center. (c) 2010 Elsevier B.V. All rights reserved.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.jorganchem.2010.09.001
语种	英语
WOS记录号	WOS:000284470900004
公开日期	2013-04-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/25333]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Cui P,Chen YF,Zhang Q,et al. Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes[J]. J. Organomet. Chem.,2010,695(25-26):2713-2719.
APA	崔鹏,陈耀峰,张强,李光玉,&夏薇.(2010).Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes.J. Organomet. Chem.,695(25-26),2713-2719.
MLA	崔鹏,et al."Synthesis, and structural characterization of solvent-free divalent ytterbium bis (boratabenzene) and (cyclopentadienyl)(boratabenzene) complexes".J. Organomet. Chem. 695.25-26(2010):2713-2719.