Structure of BaGd2(MoO4)(4) crystal | |
D. Zhao ; Z. B. Lin ; G. F. Wang | |
刊名 | Chinese Journal of Structural Chemistry
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2007 | |
卷号 | 26期号:3页码:328-332 |
关键词 | Czochralski method BaGd2(MoO4)(4) crystal mu-m |
ISSN号 | 0254-5861 |
中文摘要 | The title compound belongs to monoclinic, space group C2/c with a = 5.2694(1), b = 12.6659(4), c = 19.4108(2) angstrom, beta = 9 1.504(2)degrees, V = 1295.06(5) angstrom(3), Z = 4 and D-c = 5.599 g/cm(3). The structure of BaGd2(MoO4)(4) contains a MoO4 tetrahedron, a distorted GdO8 polyhedron, and Ba2+ ions in a tenfold coordination. The GdO8 polyhedra are linked together through edge-sharing to give a two-dimensional Gd layer. The MoO4 tetrahedra connected to the Gd atoms are capped up and down the Gd layer through common oxygen apices, thus forming a new Gd-Mo layer. Finally, the Gd-Mo layers are held together through bridging BaO10 polyhedra to form a three-dimensional framework. Since the Ba-mu(3)-O bond has a large average distance of 2.888 angstrom, this structural characteristic will result in a cleavage along the (001) plane. |
语种 | 英语 |
公开日期 | 2013-04-01 |
内容类型 | 期刊论文 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6896] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | D. Zhao,Z. B. Lin,G. F. Wang. Structure of BaGd2(MoO4)(4) crystal[J]. Chinese Journal of Structural Chemistry,2007,26(3):328-332. |
APA | D. Zhao,Z. B. Lin,&G. F. Wang.(2007).Structure of BaGd2(MoO4)(4) crystal.Chinese Journal of Structural Chemistry,26(3),328-332. |
MLA | D. Zhao,et al."Structure of BaGd2(MoO4)(4) crystal".Chinese Journal of Structural Chemistry 26.3(2007):328-332. |
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