Structure of BaGd2(MoO4)(4) crystal

	Structure of BaGd2(MoO4)(4) crystal
	D. Zhao ; Z. B. Lin ; G. F. Wang
刊名	Chinese Journal of Structural Chemistry
	2007
卷号	26 期号:3 页码:328-332
关键词	Czochralski method BaGd2(MoO4)(4) crystal mu-m
ISSN号	0254-5861
中文摘要	The title compound belongs to monoclinic, space group C2/c with a = 5.2694(1), b = 12.6659(4), c = 19.4108(2) angstrom, beta = 9 1.504(2)degrees, V = 1295.06(5) angstrom(3), Z = 4 and D-c = 5.599 g/cm(3). The structure of BaGd2(MoO4)(4) contains a MoO4 tetrahedron, a distorted GdO8 polyhedron, and Ba2+ ions in a tenfold coordination. The GdO8 polyhedra are linked together through edge-sharing to give a two-dimensional Gd layer. The MoO4 tetrahedra connected to the Gd atoms are capped up and down the Gd layer through common oxygen apices, thus forming a new Gd-Mo layer. Finally, the Gd-Mo layers are held together through bridging BaO10 polyhedra to form a three-dimensional framework. Since the Ba-mu(3)-O bond has a large average distance of 2.888 angstrom, this structural characteristic will result in a cleavage along the (001) plane.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6896]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	D. Zhao,Z. B. Lin,G. F. Wang. Structure of BaGd2(MoO4)(4) crystal[J]. Chinese Journal of Structural Chemistry,2007,26(3):328-332.
APA	D. Zhao,Z. B. Lin,&G. F. Wang.(2007).Structure of BaGd2(MoO4)(4) crystal.Chinese Journal of Structural Chemistry,26(3),328-332.
MLA	D. Zhao,et al."Structure of BaGd2(MoO4)(4) crystal".Chinese Journal of Structural Chemistry 26.3(2007):328-332.