Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol

	Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol
	Z. L. Xie ; Q. H. Wei ; L. Y. Zhang ; Z. N. Chen
刊名	Inorganic Chemistry Communications
	2007-10
卷号	10 期号:10 页码:1206-1209
关键词	alkynyl crystal structure gold luminescence silver d(10) metal-complexes silver(i) complexes alkynyl complexes coordination ag arylacetylides copper(i) moieties ligands ch3
ISSN号	1387-7003
中文摘要	Reaction of polymeric species (AgC CC5H8OH)(n)(HC CC5H8OH = 1-ethynylcyclopentanol) with binuclear precursor [Au-2(mu-dppm)(2)](PF6)(2) (dppm = bis(diphenylphospnino)methane) caused isolation of Au3Ag6 heterononanuclear complex [Au3Ag6(mu-dppm)(3)(mu(3)-eta(1)-C CC5H8OH)(6)](PF6)(3). The Au3Ag6 (mu(3)-C CC5H8OH)(6) skeleton exhibits a hexagonal prismatic structure formed by mu(3)-eta(1)-C CC5H8OH bound to the Au3Ag6 cluster core. The compound is luminescent in both solid state and dichloromethane at both 298 and 77 K with the room temperature lifetimes in microsecond ranges, suggesting an emissive triplet parentage. (c) 2007 Elsevier B.V. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6764]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	Z. L. Xie,Q. H. Wei,L. Y. Zhang,et al. Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol[J]. Inorganic Chemistry Communications,2007,10(10):1206-1209.
APA	Z. L. Xie,Q. H. Wei,L. Y. Zhang,&Z. N. Chen.(2007).Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol.Inorganic Chemistry Communications,10(10),1206-1209.
MLA	Z. L. Xie,et al."Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol".Inorganic Chemistry Communications 10.10(2007):1206-1209.