A novel hybrid solid constructed from tetramolybdate and copper complexes with mixed ligands: {(Cu center dot phen)(2)(tp)}{(Cu center dot phen center dot H2O)(2)(tp)}{Mo4O14}

	A novel hybrid solid constructed from tetramolybdate and copper complexes with mixed ligands: {(Cu center dot phen)(2)(tp)}{(Cu center dot phen center dot H2O)(2)(tp)}{Mo4O14}
	X. Y. Wu ; Q. G. Zhai ; L. J. Chen ; W. B. Yang ; C. Z. Lu
刊名	Chinese Journal of Structural Chemistry
	2007
卷号	26 期号:4 页码:389-394
关键词	polyoxometalate 1 10-phenanthroline terephthalate tetramolybdate cluster crystal structure hydrothermal synthesis crystal-structure fragments chains molybdate clusters
ISSN号	0254-5861
中文摘要	A novel copper molybdate with mixed ligands, [{(Cu center dot phen)2(tP)} {(Cu-phen center dot H2O)(2)(tp)} {Mo4O14}] (phen = 1,10-phenanthroline, tp = terephthalate) 1, has been hydrothermally synthesized and structurally characterized. The crystal belongs to monoclinic system, space group P2(l)/c with a = 13.1711(7), b = 19.6132(10), c = 13.6910(7) angstrom,beta = 117.6870(10)degrees, V= 3131.8(3) angstrom(3), Z = 2, C64H44Cu4Mo4N8O24, M-r = 1946.99, D-c 2.065 g/cm(3), F(000) = 1920, mu(MoK alpha) = 2.198 mm(-1), R = 0.0810 and wR = 0.2012 for 4233 observed reflections (I > 2 sigma(I)). The structural analysis indicates that the title compound contains a discrete tetramolybdate cluster decorated with copper complex fragments and tp ligands bridging the clusters into a wave-like layer. The hydrogen bonding between adjacent layers further extends the compound into a 3-D framework.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6755]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	X. Y. Wu,Q. G. Zhai,L. J. Chen,et al. A novel hybrid solid constructed from tetramolybdate and copper complexes with mixed ligands: {(Cu center dot phen)(2)(tp)}{(Cu center dot phen center dot H2O)(2)(tp)}{Mo4O14}[J]. Chinese Journal of Structural Chemistry,2007,26(4):389-394.
APA	X. Y. Wu,Q. G. Zhai,L. J. Chen,W. B. Yang,&C. Z. Lu.(2007).A novel hybrid solid constructed from tetramolybdate and copper complexes with mixed ligands: {(Cu center dot phen)(2)(tp)}{(Cu center dot phen center dot H2O)(2)(tp)}{Mo4O14}.Chinese Journal of Structural Chemistry,26(4),389-394.
MLA	X. Y. Wu,et al."A novel hybrid solid constructed from tetramolybdate and copper complexes with mixed ligands: {(Cu center dot phen)(2)(tp)}{(Cu center dot phen center dot H2O)(2)(tp)}{Mo4O14}".Chinese Journal of Structural Chemistry 26.4(2007):389-394.