A p-sulfonatothiacalix 4 arene supramolecular capsule containing a dinuclear copper(II) complex

	A p-sulfonatothiacalix 4 arene supramolecular capsule containing a dinuclear copper(II) complex
	M. Y. Wu ; D. Q. Yuan ; B. Q. Chen ; Y. G. Huang ; F. L. Jiang ; M. C. Hong
刊名	Supramolecular Chemistry
	2007
卷号	19 期号:6 页码:411-417
关键词	p-sulfonatothiacalix[4] arene copper supramolecular capsule crystal structure molecular capsules metal-complexes coordination encapsulation confinement superanions calixarene bilayers cations sites
ISSN号	1061-0278
中文摘要	The reaction of tetrasodium p-sulfonatothiacalix[4] arene ( Na(4)H(4)TCAS), copper( II) nitrate and pyridine N- oxide ( PNO) afforded a yellow copper( II)-p-sulfonatothiacalix[ 4] arene complex. X-ray diffraction analysis displays that it is an interesting dimeric supramolecular capsule, [Cu-2( PNO)(2)( H2O)(6)](4+), [( H(6)TCAS)(2)](4+)center dot 22H(2)O, in which two PNO molecules bridge the two Cu II ions in the O,O'- mu(2) mode and the hydrophobic aromatic rings point into the cavities of the thiacalixarenes. Interestingly, the thiacalixarenes pack themselves into the closed pores through pi center dot center dot center dot pi interactions in ab plane, and these pores further link to each other through hydrogen bonding to construct infinite hydrophilic tunnels, which fill with the disordered water molecules as the guests.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6749]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	M. Y. Wu,D. Q. Yuan,B. Q. Chen,et al. A p-sulfonatothiacalix 4 arene supramolecular capsule containing a dinuclear copper(II) complex[J]. Supramolecular Chemistry,2007,19(6):411-417.
APA	M. Y. Wu,D. Q. Yuan,B. Q. Chen,Y. G. Huang,F. L. Jiang,&M. C. Hong.(2007).A p-sulfonatothiacalix 4 arene supramolecular capsule containing a dinuclear copper(II) complex.Supramolecular Chemistry,19(6),411-417.
MLA	M. Y. Wu,et al."A p-sulfonatothiacalix 4 arene supramolecular capsule containing a dinuclear copper(II) complex".Supramolecular Chemistry 19.6(2007):411-417.