Novel copper-complex-substituted tungstogermanates

	Novel copper-complex-substituted tungstogermanates
	C. M. Wang ; S. T. Zheng ; G. Y. Yang
刊名	Inorganic Chemistry
	2007-02
卷号	46 期号:3 页码:616-618
关键词	transition-metal-complexes hydrothermal syntheses crystal-structures magnetism electrochemistry polyoxometalate polyoxoanions polyoxotungstate silicotungstate clusters
ISSN号	0020-1669
中文摘要	Two copper-complex-substituted tungstogermanates [Cu-5(2,2'-bpy)(6)(H2O)][GeW8O31]center dot 9H(2)O, 1, and {[Cu-5(2,2'-bpy)(5)(H2O)][GeW9O34]}(2)center dot 7H(2)O, 2 (2,2'-bpy = 2,2'-bipyridyl), have been hydrothermally synthesized and structurally characterized. X-ray structural analyses show that 1 is a rare tetralacunary Keggin anion of [B-beta-GeW8O31](10-) substituted by copper complexes, while dimer 2 consists of two trilacunary [B-alpha-GeW9O34](10-) Keggin units bridged by copper complexes. Magnetic measurement for 2 shows the presence of antiferromagnetic interactions within the dinuclear Cu2+ cations.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6641]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	C. M. Wang,S. T. Zheng,G. Y. Yang. Novel copper-complex-substituted tungstogermanates[J]. Inorganic Chemistry,2007,46(3):616-618.
APA	C. M. Wang,S. T. Zheng,&G. Y. Yang.(2007).Novel copper-complex-substituted tungstogermanates.Inorganic Chemistry,46(3),616-618.
MLA	C. M. Wang,et al."Novel copper-complex-substituted tungstogermanates".Inorganic Chemistry 46.3(2007):616-618.