One-dimensional copper(II) complex containing alternate single and double end-on azide ligands: Crystal structure and magnetic characterization

	One-dimensional copper(II) complex containing alternate single and double end-on azide ligands: Crystal structure and magnetic characterization
	X. Y. Song ; W. Li ; L. C. Li ; D. Z. Liao ; Z. H. Jiang
刊名	Inorganic Chemistry Communications
	2007-05
卷号	10 期号:5 页码:567-570
关键词	copper(II) crystal structure azido ligands magnetic properties manganese(ii) coordination polymers to-end antiferromagnetic interactions magnetostructural correlations bridged copper(ii) trans-oxamidate ni-ii chain behavior ferromagnetism
ISSN号	1387-7003
中文摘要	A novel one-dimensional azido-bridged coordination polymer of formula [CU2(L)(2)(H2O)(N-3)(4)](n) (1) has been synthesized and charac-terized crystallographically and magnetically, where L is 5-methylpyrimidin-2-amine. Complex 1 consists of 1D chain in which the Cu(II) ions with a square pyramidal geometry are alternately bridged by asymmetric single and symmetric double end-on (EO) azido ligands. Magnetic analysis reveals that the dominating ferromagnetic interaction is mediated by the symmetric double azido bridge with the exchange parameter J=55.17cm(-1). (c) 2007 Elsevier B.V. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6609]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	X. Y. Song,W. Li,L. C. Li,et al. One-dimensional copper(II) complex containing alternate single and double end-on azide ligands: Crystal structure and magnetic characterization[J]. Inorganic Chemistry Communications,2007,10(5):567-570.
APA	X. Y. Song,W. Li,L. C. Li,D. Z. Liao,&Z. H. Jiang.(2007).One-dimensional copper(II) complex containing alternate single and double end-on azide ligands: Crystal structure and magnetic characterization.Inorganic Chemistry Communications,10(5),567-570.
MLA	X. Y. Song,et al."One-dimensional copper(II) complex containing alternate single and double end-on azide ligands: Crystal structure and magnetic characterization".Inorganic Chemistry Communications 10.5(2007):567-570.