Copper(II) azide complexes with mono-anionic tridentate Schiff-base ligands: monomer versus dimer

	Copper(II) azide complexes with mono-anionic tridentate Schiff-base ligands: monomer versus dimer
	B. Sarkar ; M. S. Ray ; M. G. B. Drew ; C. Z. Lu ; A. Ghosh
刊名	Journal of Coordination Chemistry
	2007
卷号	60 期号:20 页码:2165-2176
关键词	copper(II) Schiff base azide crystal structure H-bonding ferromagnetic-antiferromagnetic interactions hydrogen-bond structures ray crystal-structures magnetic-properties structural-characterization nickel(ii) complexes ni-ii behavior chain dinuclear
ISSN号	0095-8972
中文摘要	Three new copper(II) complexes [(CuLN3)-N-1](2) (1), [(CuLN3)-N-2] (2) and [(CuLN3)-N-3] (3) with three very similar tridentate Schiff base ligands [HL1=6-diethylamino-3-methyl-1-phenyl-4-azahex-3-en1- one, HL2= 6-amino-3-methyl-1-phenyl-4-azahex-3-en-1-one and HL3= 6-amino-3-methyl1- phenyl-4-azasept-3-en-1-one] have been synthesized and structurally characterized by X-ray crystallography. In complex 1 half of the molecules are basal-apical, end-on azido bridged dimers and the remaining half are square-planar monomers whereas all the molecules in complexes 2 and 3 are monomers with square-planar geometry around Cu(II). A competition between the coordinate bond and H-bond seems to be responsible for the difference in structure of the complexes.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6581]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	B. Sarkar,M. S. Ray,M. G. B. Drew,et al. Copper(II) azide complexes with mono-anionic tridentate Schiff-base ligands: monomer versus dimer[J]. Journal of Coordination Chemistry,2007,60(20):2165-2176.
APA	B. Sarkar,M. S. Ray,M. G. B. Drew,C. Z. Lu,&A. Ghosh.(2007).Copper(II) azide complexes with mono-anionic tridentate Schiff-base ligands: monomer versus dimer.Journal of Coordination Chemistry,60(20),2165-2176.
MLA	B. Sarkar,et al."Copper(II) azide complexes with mono-anionic tridentate Schiff-base ligands: monomer versus dimer".Journal of Coordination Chemistry 60.20(2007):2165-2176.