NH3CH2CHCH3NH3 B8O11(OH)(4) center dot H2O: Synthesis and characterization of the first 1D borate templated by 1,2-diaminopropane

	NH3CH2CHCH3NH3 B8O11(OH)(4) center dot H2O: Synthesis and characterization of the first 1D borate templated by 1,2-diaminopropane
	C. Y. Pan ; G. M. Wang ; S. T. Zheng ; G. Y. Yang
刊名	Journal of Solid State Chemistry
	2007-05
卷号	180 期号:5 页码:1553-1558
关键词	borates hydrothermal synthesis crystal structure fundamental building-blocks crystal-structure infrared spectra lead borate chemistry minerals examples clusters chain form
ISSN号	0022-4596
中文摘要	A new hydrated borate compound, [NH3CH2CHCH3NH3]][B(8)O11(OH)(4)].H2O 1, has been synthesized in the presence of 1,2diaminopropane acting as a structure-directing agent under mild conditions. Its structure was determined by single crystal X-ray diffraction and further characterized FTIR, elemental analysis, powder X-ray diffraction and thermogravimetric analysis. Compound I crystallizes in the monoclinic system, space group P21/c (No. 14), a = 10.0787(7)angstrom, b = 8.8482(6) angstrom, c = 19.3097(4) angstrom, beta = 91.352(6)degrees, V = 1721.53(2)angstrom(3), and Z = 4. The structure consists of infinite open-branched borate chains constructed from [B3O6(OH)] units, onto which the [B5O7(OH)(3)] groups are grafted. It represents the first example of one-dimensional borate templated by an organic amine. The adjacent borate chains are further linked together by extensive hydrogen bonds to form a 3D supramolecular network. The diprotonated organic amines and guest water molecules are filled in the free space of the hydrogen-bonded network and interact with the inorganic framework by extensive hydrogen bonds. (C) 2007 Elsevier Inc. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6549]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	C. Y. Pan,G. M. Wang,S. T. Zheng,et al. NH3CH2CHCH3NH3 B8O11(OH)(4) center dot H2O: Synthesis and characterization of the first 1D borate templated by 1,2-diaminopropane[J]. Journal of Solid State Chemistry,2007,180(5):1553-1558.
APA	C. Y. Pan,G. M. Wang,S. T. Zheng,&G. Y. Yang.(2007).NH3CH2CHCH3NH3 B8O11(OH)(4) center dot H2O: Synthesis and characterization of the first 1D borate templated by 1,2-diaminopropane.Journal of Solid State Chemistry,180(5),1553-1558.
MLA	C. Y. Pan,et al."NH3CH2CHCH3NH3 B8O11(OH)(4) center dot H2O: Synthesis and characterization of the first 1D borate templated by 1,2-diaminopropane".Journal of Solid State Chemistry 180.5(2007):1553-1558.