Structures and luminescent properties of lanthanide phosphonates

	Structures and luminescent properties of lanthanide phosphonates
	J. G. Mao
刊名	Coordination Chemistry Reviews
	2007-06
卷号	251 期号:11-12 页码:1493-1520
关键词	syntheses crystal structures rare earth phosphonates open frameworks luminescence initio structure determination ray crystal-structure frameworks mil-n hydrothermal synthesis carboxylate-phosphonates metal phosphonates network structure 3d network complexes acid
ISSN号	0010-8545
中文摘要	The crystal structures and luminescent properties of lanthanide phosphonates are reviewed. The structural elucidation for lanthanide phosphonates is difficult due to its low solubility and poor crystallinity. To overcome these problems, two types of synthetic techniques were applied: attaching various functional groups or introducing a second metal linker. By attaching various types of functional groups to the phosphonate ligand, lanthanide phosphonates with 0D, ID, 2D and 3D structures have been isolated. Using the acidic metal linker such as oxalate usually leads to compounds with a complicated 3D network structure whereas a basic second metal linker such as phen helps the formation of compounds containing the polynuclear clusters. Phosphonic acids are versatile ligands that can adopt a number of coordination modes depending on the cation size, temperature and the pH value of the reaction media. The luminescence properties of some lanthanide phosphonates are also discussed. (C) 2007 Elsevier B.V. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6534]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	J. G. Mao. Structures and luminescent properties of lanthanide phosphonates[J]. Coordination Chemistry Reviews,2007,251(11-12):1493-1520.
APA	J. G. Mao.(2007).Structures and luminescent properties of lanthanide phosphonates.Coordination Chemistry Reviews,251(11-12),1493-1520.
MLA	J. G. Mao."Structures and luminescent properties of lanthanide phosphonates".Coordination Chemistry Reviews 251.11-12(2007):1493-1520.