Hydrolysis to the first dumbbell-like high-nuclearity bismuth-oxo cluster Bi-12(mu(3)-OH)(4)(mu(2)-OH)(2)(mu(3)-O)(8)(mu(4)-O)(2)(NO3)(6) (4+): Synthesis, structure and spectroscopic characterizations

	Hydrolysis to the first dumbbell-like high-nuclearity bismuth-oxo cluster Bi-12(mu(3)-OH)(4)(mu(2)-OH)(2)(mu(3)-O)(8)(mu(4)-O)(2)(NO3)(6) (4+): Synthesis, structure and spectroscopic characterizations
	B. Liu ; W. W. Zhou ; Z. Q. Zhou ; X. Y. Zhang
刊名	Inorganic Chemistry Communications
	2007-10
卷号	10 期号:10 页码:1145-1148
关键词	Bismuth(III) crystal structure fluorescence band gap ferroelectric thin-films ray crystal-structures solid-state structures molecular-structure metal-oxide precursors complexes alkoxides photoluminescence srbi2ta2o9
ISSN号	1387-7003
中文摘要	The first dumbbell-like high-nuclearity bismuth-oxo cluster [Bi-12(mu(3)-OH)(4)(mu(2)-OH)(2)(mu(3)-O)(8)(mu(4)-O)(2)(NO3)(6)](NO3)(4)center dot 6H(2)O was obtained by diffusing ethanol into the hydrolysate of Bi(NO3)(3) aqueous solution. The dumbbell consists of two Bi-O bonds as the handle and two [Bi-6(mu(3)-OH)(2)(mu(2)-OH)(mu(3)-O)(4)(mu(4)-O)] subunits as the bells. The bell can be regarded as a piercing bracelet-like ring consisted of six edge-sharing tetragons with one cross section enveloped by one mu(3)-O linking three Bi(111) atoms and the other connected by one mu(2)-O as a open cover. The structure is further stabilized by the interactions of Bi...Bi, Bi...O and hydrogen bondings. The optical gap of 2.85 eV suggests that the title compound behaves as semiconductors. The title compound features a blue fluorescence at 441 nm, which is assigned to P-1(1)-S-1(0) and P-3-S-1(0), transitions from the s(2) electron of Bi3+ cation. (c) 2007 Elsevier B.V. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6465]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	B. Liu,W. W. Zhou,Z. Q. Zhou,et al. Hydrolysis to the first dumbbell-like high-nuclearity bismuth-oxo cluster Bi-12(mu(3)-OH)(4)(mu(2)-OH)(2)(mu(3)-O)(8)(mu(4)-O)(2)(NO3)(6) (4+): Synthesis, structure and spectroscopic characterizations[J]. Inorganic Chemistry Communications,2007,10(10):1145-1148.
APA	B. Liu,W. W. Zhou,Z. Q. Zhou,&X. Y. Zhang.(2007).Hydrolysis to the first dumbbell-like high-nuclearity bismuth-oxo cluster Bi-12(mu(3)-OH)(4)(mu(2)-OH)(2)(mu(3)-O)(8)(mu(4)-O)(2)(NO3)(6) (4+): Synthesis, structure and spectroscopic characterizations.Inorganic Chemistry Communications,10(10),1145-1148.
MLA	B. Liu,et al."Hydrolysis to the first dumbbell-like high-nuclearity bismuth-oxo cluster Bi-12(mu(3)-OH)(4)(mu(2)-OH)(2)(mu(3)-O)(8)(mu(4)-O)(2)(NO3)(6) (4+): Synthesis, structure and spectroscopic characterizations".Inorganic Chemistry Communications 10.10(2007):1145-1148.