Three novel trinuclear zinc(II)/nickel(II) complexes with pentadentate ligands N-nitrobenzoylsalicylhydrazidate

	Three novel trinuclear zinc(II)/nickel(II) complexes with pentadentate ligands N-nitrobenzoylsalicylhydrazidate
	S. Lin ; M. X. Yang ; S. X. Liu
刊名	Polyhedron
	2007-10
卷号	26 期号:17 页码:4793-4798
关键词	N-nitrobenzoylsalicylhydrazides zinc nickel polynuclear metal complex magnetic-properties crystal-structure schiff-base nickel(ii) complexes structural-characterization molecular-structure hexanuclear nuclearity metallamacrocycle dinuclear
ISSN号	0277-5387
中文摘要	Three trinuclear zinc(II)/nickel(II) complexes with two pentadentate ligands, N-p-nitrobenzoylsalicylhydrazidate (H-3-p-nbzshz) and N-o-nitrobenzoylsalicylhydrazidate (H-3-o-nbzshz) have been synthesized and characterized by X-ray crystallography. The complex [Zn-3(p-nbzshz)(2)(C5H5N)(4)](n) (1) molecule exhibits a one-dimensional wave-like chain structure resulting from the linkage of phenolate oxygen donor atoms of the ligands between neighboring motifs. The two nickel(II) complexes, Ni-3(p-nbzshz)(2)(C5H5N)(4) (2) and Ni-3(o-nbzshz)(2)(C3H7NO)(2)(C2H6O)(2) (3) are trinuclear complexes in which three nickel(II) centers exhibit alternating square-planar and octahedral geometries. Complex 2 exhibits a curved Ni-3 metal arrangement with a Ni(1)-Ni(2)-Ni(3) angle of 62.36 degrees, while the three nickel atoms in complex 3 are strictly linear with an angle of 180 degrees. (C) 2007 Elsevier Ltd. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6452]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	S. Lin,M. X. Yang,S. X. Liu. Three novel trinuclear zinc(II)/nickel(II) complexes with pentadentate ligands N-nitrobenzoylsalicylhydrazidate[J]. Polyhedron,2007,26(17):4793-4798.
APA	S. Lin,M. X. Yang,&S. X. Liu.(2007).Three novel trinuclear zinc(II)/nickel(II) complexes with pentadentate ligands N-nitrobenzoylsalicylhydrazidate.Polyhedron,26(17),4793-4798.
MLA	S. Lin,et al."Three novel trinuclear zinc(II)/nickel(II) complexes with pentadentate ligands N-nitrobenzoylsalicylhydrazidate".Polyhedron 26.17(2007):4793-4798.