A one-dimensional azido-bridged manganese(III) complex with bidentate Schiff base: Crystal structure and magnetic properties

	A one-dimensional azido-bridged manganese(III) complex with bidentate Schiff base: Crystal structure and magnetic properties
	W. Li ; Z. W. Li ; L. C. Li ; D. Z. Liao ; Z. H. Jang
刊名	Journal of Solid State Chemistry
	2007-10
卷号	180 期号:10 页码:2973-2977
关键词	manganese(III) complex azido-bridged one-dimensional complex crystal structure magnetic properties end-to-end ni-ii chain behavior mn(salpn)n-3 copper(ii) exchange polymer dimer
ISSN号	0022-4596
中文摘要	The synthesis, structural characterization, and magnetic behavior of a novel one-dimensional azido-bridged manganese(III) complex of formula [Mn(L)(2)N-3] (1) is reported, where HL is the bidentate Schiff base obtained from the condensation of salicylaldehyde with methoxy aniline. Complex 1 crystallizes in the monoclinic system, space group P2(1)/n, with a = 11.743(4)angstrom, b = 24.986(9)angstrom, c = 13.081(5)angstrom, beta = 95.387(7)degrees and Z = 2. The complex is of one-dimensional chain structure with single end-to-end azido bridges and the manganese(III) ion has an elongated octahedral geometry. Magnetic Studies show that the weak antiferromagnetic interaction is mediated by the single end-to-end azido bridge with the exchange parameter J = -5.84 cm(-1). (C) 2007 Elsevier Inc. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6415]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	W. Li,Z. W. Li,L. C. Li,et al. A one-dimensional azido-bridged manganese(III) complex with bidentate Schiff base: Crystal structure and magnetic properties[J]. Journal of Solid State Chemistry,2007,180(10):2973-2977.
APA	W. Li,Z. W. Li,L. C. Li,D. Z. Liao,&Z. H. Jang.(2007).A one-dimensional azido-bridged manganese(III) complex with bidentate Schiff base: Crystal structure and magnetic properties.Journal of Solid State Chemistry,180(10),2973-2977.
MLA	W. Li,et al."A one-dimensional azido-bridged manganese(III) complex with bidentate Schiff base: Crystal structure and magnetic properties".Journal of Solid State Chemistry 180.10(2007):2973-2977.