A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: Synthesis, crystal structure and properties of (Hapy)(4) Co(H2O)(5)Mo7O24 center dot 9H(2)O

	A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: Synthesis, crystal structure and properties of (Hapy)(4) Co(H2O)(5)Mo7O24 center dot 9H(2)O
	T. H. Li ; H. Lu ; S. Y. Gao ; R. Cao
刊名	Inorganic Chemistry Communications
	2007-11
卷号	10 期号:11 页码:1342-1346
关键词	supported polyoxometalate heptamolybdate anions supramolecular magnetic property electrochemical property hydrothermal synthesis coordination polymers composite-solids hydrogen-bond clusters polyoxometalate complexes octamolybdate catalysis ligands
ISSN号	1387-7003
中文摘要	A new supramolecular compound based on the heptamolybdate anion, formulated as (HaPY)(4)[Co(H2O)(5)Mo7O24]center dot 9H(2)O (1) (apy = 2-aminopyridine), has been synthesized hydrothermally and characterized by elemental analyses, IR, and X-ray single crystal diffraction. Compound 1 crystallizes as alternating layers of inorganic anions and organic cations linked by hydrogen-bonding interactions. A variable-temperature magnetic susceptibility measurement of 1 demonstrated the presence of antiferromagnetic interactions. Furthermore, the cyclic voltammograin of I shows two reversible redox couples both of which are associated with two-electron processes of molybdenum. (c) 2007 Elsevier B.V. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6407]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	T. H. Li,H. Lu,S. Y. Gao,et al. A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: Synthesis, crystal structure and properties of (Hapy)(4) Co(H2O)(5)Mo7O24 center dot 9H(2)O[J]. Inorganic Chemistry Communications,2007,10(11):1342-1346.
APA	T. H. Li,H. Lu,S. Y. Gao,&R. Cao.(2007).A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: Synthesis, crystal structure and properties of (Hapy)(4) Co(H2O)(5)Mo7O24 center dot 9H(2)O.Inorganic Chemistry Communications,10(11),1342-1346.
MLA	T. H. Li,et al."A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: Synthesis, crystal structure and properties of (Hapy)(4) Co(H2O)(5)Mo7O24 center dot 9H(2)O".Inorganic Chemistry Communications 10.11(2007):1342-1346.