Syntheses, crystal structures and photo luminescence properties of three novel organically bonded indium selenates or selenites

	Syntheses, crystal structures and photo luminescence properties of three novel organically bonded indium selenates or selenites
	M. L. Feng ; H. Y. Ye ; J. G. Mao
刊名	Journal of Solid State Chemistry
	2007-09
卷号	180 期号:9 页码:2471-2477
关键词	hydro/solvothermal syntheses layered materials indium selenates or selenites in suit ligand synthesis crystal structures hydrothermal syntheses phosphates co chemistry solids ni
ISSN号	0022-4596
中文摘要	Three new organically bonded indium(III) selenates or selenites, namely, In-2(2,2 '-bipy)(2)(SeO4)(3)(H2O)(2)center dot 2H(2)O (1), In-2(2,2 '-bipy)(2) (SeO4)(C2O4)(2)center dot 0.5H(2)O (2) and In-2(2,2 '-bipy)(2)(SeO3)(2)(C2O4) (3) (2,2 '-bipy = 2,2 '-bipyridine) have been synthesized by hydro/solvothermal reactions by using the in situ ligand synthesis technique (2 and 3) and structurally characterized. The structure of compound 1 features a dimer composed of two InO4N2 octahedra bridged by three SeO4 tetrahedra via cornering sharing. The structure of compound 2 shows a 2D inorganic-organic hybrid layer in which the indium (III) ions are bridged by both selenate and oxalate anions, whereas the structure of compound 3 possesses a 2D inorganic-organic hybrid layer composed of the indium (III) ions interconnected by both selenite and oxalate anions. The adjacent layers are further interconnected via pi...pi interactions between the bipy ligands. Compound 1 displays an intra-ligand luminescent emission band at lambda(max) = 360 rim whereas compounds 2 and 3 both exhibit intra-ligand luminescent emission bands at lambda(max) = 389 nm. (c) 2007 Elsevier Inc. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6243]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	M. L. Feng,H. Y. Ye,J. G. Mao. Syntheses, crystal structures and photo luminescence properties of three novel organically bonded indium selenates or selenites[J]. Journal of Solid State Chemistry,2007,180(9):2471-2477.
APA	M. L. Feng,H. Y. Ye,&J. G. Mao.(2007).Syntheses, crystal structures and photo luminescence properties of three novel organically bonded indium selenates or selenites.Journal of Solid State Chemistry,180(9),2471-2477.
MLA	M. L. Feng,et al."Syntheses, crystal structures and photo luminescence properties of three novel organically bonded indium selenates or selenites".Journal of Solid State Chemistry 180.9(2007):2471-2477.