Intercalation of cation guests into a three-dimensional anionic host framework | |
J. K. Cheng ; P. X. Yin ; Z. J. Li ; Y. Y. Qin ; Y. G. Yao | |
刊名 | Inorganic Chemistry Communications
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2007-07 | |
卷号 | 10期号:7页码:808-810 |
关键词 | supramolecular bis(2 host framework 9-dimethyl-1 photo-luminescence 10-phenanthroline)copper(i) hydrothermal reaction metal-organic framework nitrate polymer components crystal |
ISSN号 | 1387-7003 |
中文摘要 | A new three-dimensional photoluminescent host-guest open-framework, {[Cu(dmp)(2)(+)] center dot [1/2(H(2)bdc) center dot 1/2(bdc(2-)) center dot 2H(2)O]}(n) (1) (dmp = 2,9-dimethyl-1,10-phenanthroline, bdc = 1,4-benzene-dicarboxylate), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR spectrum, fluorescent spectrum, and thermogravimetric analyses. The structure of complex 1 features a three-dimensional supramolecular host architecture with photosensitizer-dye cation guests. Although Cu2+ was used as the starting material, no obvious signal was observed in ESR spectrum of 1, which indicates that all copper atoms in 1 are Cu+ and redox reaction occurred under the present hydrothermal condition. (c) 2007 Elsevier B.V. All rights reserved. |
语种 | 英语 |
公开日期 | 2013-04-01 |
内容类型 | 期刊论文 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6194] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | J. K. Cheng,P. X. Yin,Z. J. Li,et al. Intercalation of cation guests into a three-dimensional anionic host framework[J]. Inorganic Chemistry Communications,2007,10(7):808-810. |
APA | J. K. Cheng,P. X. Yin,Z. J. Li,Y. Y. Qin,&Y. G. Yao.(2007).Intercalation of cation guests into a three-dimensional anionic host framework.Inorganic Chemistry Communications,10(7),808-810. |
MLA | J. K. Cheng,et al."Intercalation of cation guests into a three-dimensional anionic host framework".Inorganic Chemistry Communications 10.7(2007):808-810. |
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