A novel 3D network structure constructed from centrosymmetric sodium-phosphomolybdate bonding by sodium and zinc atoms

	A novel 3D network structure constructed from centrosymmetric sodium-phosphomolybdate bonding by sodium and zinc atoms
	X. Q. Chen ; S. Lin ; L. J. Chen ; X. H. Chen ; C. L. Liu ; J. B. Chen ; L. Y. Yang
刊名	Inorganic Chemistry Communications
	2007-11
卷号	10 期号:11 页码:1285-1288
关键词	polyoxometalates hydrothermal synthesis 3D framework photocatalysis organic hybrid materials hydrothermal synthesis molybdenum(v) phosphate photocatalytic degradation coordination cations vanadium phosphate open-framework built-up clusters molybdophosphate
ISSN号	1387-7003
中文摘要	A novel molybdenum (V) phosphate compound, (NH3CH2CH2NH3) (NH3CH2CH2NH2)(4)Zn2Na(2){Na(1)[Mo6O16(HPO4)(3)-(PO4)(OH)(3)(H2O)](2)} center dot 3 H2O was synthesized hydrothermally and characterized by elemental analysis, IR, TG-DTA, DRS, BET and single crystal X-ray diffraction. In this compound, the centrosymmetric Na(1)[Mo(6)p(4)](2) clusters are linked by Na(2) to produce one-dimensional chains along b axis. Then such ID chains are further connected by [ZnO4] tetrahedra to construct a three-dimensional (3D) framework with channels occupied by protonated ethylenediamine ions and the water molecules. Photocatalytic reduction of Rhodamine B (RB) in a liquid-solid system shows that the title compound has high photocatalytic activity. (c) 2007 Elsevier B.V. All rights reserved.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6170]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	X. Q. Chen,S. Lin,L. J. Chen,et al. A novel 3D network structure constructed from centrosymmetric sodium-phosphomolybdate bonding by sodium and zinc atoms[J]. Inorganic Chemistry Communications,2007,10(11):1285-1288.
APA	X. Q. Chen.,S. Lin.,L. J. Chen.,X. H. Chen.,C. L. Liu.,...&L. Y. Yang.(2007).A novel 3D network structure constructed from centrosymmetric sodium-phosphomolybdate bonding by sodium and zinc atoms.Inorganic Chemistry Communications,10(11),1285-1288.
MLA	X. Q. Chen,et al."A novel 3D network structure constructed from centrosymmetric sodium-phosphomolybdate bonding by sodium and zinc atoms".Inorganic Chemistry Communications 10.11(2007):1285-1288.