Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands

	Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands
	Yang WT ; Guo M ; Yi FY ; Sun ZM
刊名	crystal growth & design
	2012
卷号	12 期号:11 页码:5529-5534
关键词	SEPARATION STORAGE INTERPENETRATION TRANSFORMATION RECOGNITION CATENATION ISOMERS
ISSN号	1528-7483
通讯作者	sun zm
中文摘要	solvothermal assembly of co(ii) ion, a semirigid tetrahedral carboxylate ligand tetrakis[(4-carboxyphenyl)oxamethyl]methane acid (h4l), and rigid linear bidentate linker 1,4-di(1h-imidazol-1-yl)benzene (dib) or 4,4'-di(1h-imidazol-1-yl)-1,1'-biphenyl (dibp) yields four novel metal-organic frameworks (1-4) with different topological connections. [co-2(l)(dib)]center dot 3dmf (1) is a 2-fold interpenetrating sqc422 network and contains 3-dimensional interconnected channels along [100], [010], and [110] directions; [co-4(l)(2)(dib)(3)(h2o)(4)]center dot 4h(2)o (2) is a three-dimensional 3,4,4 connected new topology with 5-fold interpenetration; [co-2(1-)(dibp)]center dot 5dmf (3) and co-2(l)(dibp)2 (4) are formed in the presence of dibp linker; they feature three-dimensional novel topologies based on 4,6 connection and 4,4 connection, respectively, and no interpenetration is observed. it is demonstrated that interpenetration is accessible simply by changing auxiliary ligands and solvents. magnetic studies reveal that complexes 1 and 3 exhibit antiferromagnetic behavior.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000311240100046
公开日期	2013-03-18
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/47860]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Yang WT,Guo M,Yi FY,et al. Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands[J]. crystal growth & design,2012,12(11):5529-5534.
APA	Yang WT,Guo M,Yi FY,&Sun ZM.(2012).Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands.crystal growth & design,12(11),5529-5534.
MLA	Yang WT,et al."Construction of Three-Dimensional Cobalt(II)-Based Metal-Organic Frameworks by Synergy between Rigid and Semirigid Ligands".crystal growth & design 12.11(2012):5529-5534.