Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones

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	Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones
	Zhao YC(赵延川) ; Huang WZ(黄维洲) ; Zhu LG(朱林桂) ; Hu JB(胡金波)
刊名	Org. Lett.
	2010
卷号	12 期号:7 页码:1444-1447
ISSN号	1523-7060
其他题名	二氟甲基(2-吡啶基)砜: 一种适用于醛和酮的二氟烯基化试剂
通讯作者	胡金波
英文摘要	Difluoromethyl 2-pyridyl sulfone, a previously unknown compound, was found to act as a novel and efficient gem-difluoroolefination reagent for both aldehydes and ketones. It was found that the fluorinated sulfinate intermediate in the reaction is relatively stable, which can be observed by F-19 NMR and trapped with CH3I.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol100090r
语种	英语
WOS记录号	WOS:000275885400018
公开日期	2013-03-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/24075]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Zhao YC,Huang WZ,Zhu LG,et al. Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones[J]. Org. Lett.,2010,12(7):1444-1447.
APA	赵延川,黄维洲,朱林桂,&胡金波.(2010).Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones.Org. Lett.,12(7),1444-1447.
MLA	赵延川,et al."Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones".Org. Lett. 12.7(2010):1444-1447.