Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of alpha-(phenylsulfonyl)difluoromethylated benzoates

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	Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of alpha-(phenylsulfonyl)difluoromethylated benzoates
	Zhang LJ(张来俊) ; Li Y(李亚) ; Hu JB(胡金波)
刊名	J. Fluor. Chem.
	2007
卷号	128 期号:7 页码:755-761
ISSN号	0022-1139
其他题名	通过对含α-苯磺酰二氟甲基得的苯甲酸酯的脱砜基制备1-芳基-2,2-二氟-烯基酯
通讯作者	胡金波
英文摘要	1-Aryl-2,2-difluoro enol benzoates 4 has been prepared from alpha-(phenylsulfonyl)-difluoromethylated benzoates 3, which can be readily obtained from the reactions between simple aldehydes and PhSO2CF2H (or TMSCF2SO2Ph). 2,2-Difluoro enol esters 4 are relatively more stable compounds than 2,2-difluoro enol sily ethers, and they promise to act as interesting fluorinated building blocks for further elaborations. (c) 2007 Elsevier B.V. All rights reserved.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.jfluchem.2007.03.004
语种	英语
WOS记录号	WOS:000248429900013
公开日期	2013-03-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/24015]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Zhang LJ,Li Y,Hu JB. Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of alpha-(phenylsulfonyl)difluoromethylated benzoates[J]. J. Fluor. Chem.,2007,128(7):755-761.
APA	张来俊,李亚,&胡金波.(2007).Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of alpha-(phenylsulfonyl)difluoromethylated benzoates.J. Fluor. Chem.,128(7),755-761.
MLA	张来俊,et al."Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of alpha-(phenylsulfonyl)difluoromethylated benzoates".J. Fluor. Chem. 128.7(2007):755-761.