Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and Sulfides

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	Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and Sulfides
	Prakash, G. K. Surya ; Hu JB(胡金波)
刊名	Accounts Chem. Res.
	2007
卷号	40 期号:10 页码:921-930
ISSN号	0001-4842
其他题名	利用含氟砜、亚砜、硫醚类物质进行选择性氟烷基化
通讯作者	Prakash, G. K. Surya
英文摘要	Efficient fluoroalkylations have been proven to be a highly useful strategy for the synthesis of bioactive fluorine-containing compounds and other materials. The design and use of a single category of reagents for multiple synthetic goals are much more attractive to preparative organic chemists. In this Account, we show how we have succeeded in the nucleophilic trifluoromethylation, difluoromethylation, difluoromethylenation, (phenylsulfonyl)difluoromethylation, (phenylthio)difluoromethylation, and monofluoromethylation as well as radical (phenylsulfonyl)difluoromethylation and electrophilic difluoromethylation by using fluorinated sulfones, sulfoxides, sulfides, or fluorinated sulfonium salts. The chemistry not only provides practically powerful synthetic methods, but the molecular design concept that we have developed may also be adopted to tackle other related chemical problems.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ar700149s
语种	英语
WOS记录号	WOS:000250260800001
公开日期	2013-03-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/24013]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Prakash, G. K. Surya,Hu JB. Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and Sulfides[J]. Accounts Chem. Res.,2007,40(10):921-930.
APA	Prakash, G. K. Surya,&胡金波.(2007).Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and Sulfides.Accounts Chem. Res.,40(10),921-930.
MLA	Prakash, G. K. Surya,et al."Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and Sulfides".Accounts Chem. Res. 40.10(2007):921-930.