Highly regioselective rearrangement of 2-substituted vinylepoxides catalyzed by gallium(III) triflate

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	Highly regioselective rearrangement of 2-substituted vinylepoxides catalyzed by gallium(III) triflate
	Deng XM(邓贤明) ; Sun XL(孙秀丽) ; Tang Y(唐勇)
刊名	J. Org. Chem.
	2005
卷号	70 期号:16 页码:6537-6540
ISSN号	0022-3263
其他题名	Ca(oTf)3催化的2-取代乙烯基环氧的高区域选择性的重排反应
通讯作者	唐勇
英文摘要	Gallium(III) triflate catalyzed the rearrangement of 2-substituted vinylepoxides into beta,gamma-unsaturated carbonyl compounds with high regio- and chemoselectivity (> 97/3) in low catalyst loading (1-5 mol %). The alkyl-substituted trimethylsilylvinyl epoxides gave beta,gamma-unsaturated ketone, but aryl-substituted vinylepoxides gave the aldehydes instead.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo050810z
语种	英语
WOS记录号	WOS:000230909100058
公开日期	2013-02-25
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/19297]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Deng XM,Sun XL,Tang Y. Highly regioselective rearrangement of 2-substituted vinylepoxides catalyzed by gallium(III) triflate[J]. J. Org. Chem.,2005,70(16):6537-6540.
APA	邓贤明,孙秀丽,&唐勇.(2005).Highly regioselective rearrangement of 2-substituted vinylepoxides catalyzed by gallium(III) triflate.J. Org. Chem.,70(16),6537-6540.
MLA	邓贤明,et al."Highly regioselective rearrangement of 2-substituted vinylepoxides catalyzed by gallium(III) triflate".J. Org. Chem. 70.16(2005):6537-6540.