Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes | |
Qiu SF(邱水发) ; Xu T(徐涛) ; Zhou J(周娟) ; Guo YL(郭寅龙) ; Liu GS(刘国生) | |
刊名 | J. Am. Chem. Soc.
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2010 | |
卷号 | 132期号:9页码:2856-2857 |
ISSN号 | 0002-7863 |
其他题名 | 钯催化的苯乙烯分子内氨基氟化反应 |
通讯作者 | 刘国生 |
英文摘要 | A novel palladium-catalyzed intermolecular aminofluorination of styrenes, with N-fluorobenzenesulfonimide (NFSI) functioning not only as a fluorinating reagent but also as an aminating reagent, has been developed. The reaction afforded vicinal fluoroamine products With very high regioselectivity. This transformation may involve fluoropalladation of styrene as a key step for C-F bond formation, The bidental nitrogen ligand is crucial to achieving the transformation successfully. |
学科主题 | 有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/ja909716k |
语种 | 英语 |
WOS记录号 | WOS:000275660500005 |
公开日期 | 2013-02-25 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/20024] ![]() |
专题 | 上海有机化学研究所_分析化学研究室 |
推荐引用方式 GB/T 7714 | Qiu SF,Xu T,Zhou J,et al. Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes[J]. J. Am. Chem. Soc.,2010,132(9):2856-2857. |
APA | 邱水发,徐涛,周娟,郭寅龙,&刘国生.(2010).Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes.J. Am. Chem. Soc.,132(9),2856-2857. |
MLA | 邱水发,et al."Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes".J. Am. Chem. Soc. 132.9(2010):2856-2857. |
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