Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry

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	Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry
	Zhou J(周静) ; Tang W(唐伟) ; Guo YL(郭寅龙) ; Ding YX(丁贻祥)
刊名	Chin. J. Chem.
	2009
卷号	27 期号:9 页码:1733-1740
ISSN号	1001-604X
其他题名	电喷雾质谱法研究钯催化的o-Alkynylphenylphosphonamide与 N-(o-Alkynylphenyl)acetamide 分子内环化反应机理
通讯作者	郭寅龙 ; 丁贻祥
英文摘要	The intramolecular cyclization of o-alkynylphenylphosphonamide and N-(o-alkynylphenyl)acetamide was monitored by electrospray ionization mass spectrometry (ESI-MS) and its tandem version (ESI-MS/MS). The proposed intermediates were successfully intercepted and characterized. In addition, the intermediates composed of the substrate coordinated to the palladium(II) center in the reaction of o-alkynylphenylphosphonamide were unexpected before, and this interesting phenomenon of the substrate coordination seems associated with the unique structure of substrates.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/cjoc.200990292
语种	英语
WOS记录号	WOS:000270211000017
公开日期	2013-02-25
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/19978]
专题	上海有机化学研究所_分析化学研究室
推荐引用方式 GB/T 7714	Zhou J,Tang W,Guo YL,et al. Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry[J]. Chin. J. Chem.,2009,27(9):1733-1740.
APA	周静,唐伟,郭寅龙,&丁贻祥.(2009).Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry.Chin. J. Chem.,27(9),1733-1740.
MLA	周静,et al."Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry".Chin. J. Chem. 27.9(2009):1733-1740.