Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry | |
Zhou J(周静) ; Tang W(唐伟) ; Guo YL(郭寅龙) ; Ding YX(丁贻祥) | |
刊名 | Chin. J. Chem.
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2009 | |
卷号 | 27期号:9页码:1733-1740 |
ISSN号 | 1001-604X |
其他题名 | 电喷雾质谱法研究钯催化的o-Alkynylphenylphosphonamide与 N-(o-Alkynylphenyl)acetamide 分子内环化反应机理 |
通讯作者 | 郭寅龙 ; 丁贻祥 |
英文摘要 | The intramolecular cyclization of o-alkynylphenylphosphonamide and N-(o-alkynylphenyl)acetamide was monitored by electrospray ionization mass spectrometry (ESI-MS) and its tandem version (ESI-MS/MS). The proposed intermediates were successfully intercepted and characterized. In addition, the intermediates composed of the substrate coordinated to the palladium(II) center in the reaction of o-alkynylphenylphosphonamide were unexpected before, and this interesting phenomenon of the substrate coordination seems associated with the unique structure of substrates. |
学科主题 | 有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/cjoc.200990292 |
语种 | 英语 |
WOS记录号 | WOS:000270211000017 |
公开日期 | 2013-02-25 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/19978] ![]() |
专题 | 上海有机化学研究所_分析化学研究室 |
推荐引用方式 GB/T 7714 | Zhou J,Tang W,Guo YL,et al. Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry[J]. Chin. J. Chem.,2009,27(9):1733-1740. |
APA | 周静,唐伟,郭寅龙,&丁贻祥.(2009).Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry.Chin. J. Chem.,27(9),1733-1740. |
MLA | 周静,et al."Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry".Chin. J. Chem. 27.9(2009):1733-1740. |
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