[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 中科院有机氟化学重点实验室

	[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)
	Li WY(李文瑛) ; Mao LS(毛礼胜) ; Lv L(吕龙) ; He HW(贺红武)
刊名	Acta Crystallogr. Sect. E.-Struct Rep. Online
	2008
卷号	64 页码:M490-U544
ISSN号	1600-5368
其他题名	[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)
通讯作者	吕龙
英文摘要	In the title compound, [Ir(C10H8N3)(C11H8N)(2)], the Ir center is octahedrally coordinated by the three chelating ligands, with two cyclometalated 2-pyridylphenyl ligands [Ir-N = 2.049 (5) and 2.030 (5) angstrom; Ir-C = 2.016 (6) and 2.012 (6) angstrom] and a bidentate 2-(phenyldiazenyl) pyrrolate ligand [Ir-N = 2.204 (5) and 2.079 (5) angstrom]. The Ir-N(diazenyl) bond is longer than the Ir-N(pyrrolate) bond. The structure is stabilized by aromatic pi-pi stacking, the shortest parallel distance between ring centroids being 3.426 (8) angstrom.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1107/S1600536808004443
语种	英语
WOS记录号	WOS:000253792100041
公开日期	2013-02-25
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/19193]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Li WY,Mao LS,Lv L,et al. [2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)[J]. Acta Crystallogr. Sect. E.-Struct Rep. Online,2008,64:M490-U544.
APA	李文瑛,毛礼胜,吕龙,&贺红武.(2008).[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III).Acta Crystallogr. Sect. E.-Struct Rep. Online,64,M490-U544.
MLA	李文瑛,et al."[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)".Acta Crystallogr. Sect. E.-Struct Rep. Online 64(2008):M490-U544.