Theoretical Studies of ESR Parameters and Local Lattice Structure of the Vanadate-Lithium-Borate Glasses

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	Theoretical Studies of ESR Parameters and Local Lattice Structure of the Vanadate-Lithium-Borate Glasses
	W. L. Feng ; M. F. Zhao ; T. Li ; X. H. Zhang ; J. Y. Xue
刊名	Acta Physica Polonica A
	2012
卷号	122 期号:1 页码:167-169
关键词	electron-spin-resonance atomic screening constants optical-spectra phosphate-glasses paramagnetic resonance hamiltonian parameters superposition-model epr parameters scf functions vo2+ ions
ISSN号	0587-4246
中文摘要	Electron spin resonance spectral parameters of V4+ ions in vanadate-lithium-borate glasses have been calculated by the crystal-field theory. The theoretical results are g(parallel to) = 1.940, g(perpendicular to) = 1.983 and A(parallel to) = -175 x 10(-4) cm(-1), A perpendicular to = -65 x 10(-4) cm(-1) which are good agreement with the experimental values (g(parallel to) = 1.939(3), g(perpendicular to) = 1.998(3) and A(parallel to) = (170.6-176.4) x 10(-4) cm(-1), A(perpendicular to) = (61.3-71.4) x 10(-4) cm(-1)). In addition, the bond lengths of the local lattice structure are, respectively, R-parallel to = 1.5 angstrom and R-perpendicular to = 1.95 angstrom which have been shown to have a compressed tetrahedral geometry along the C-4 axis.
原文出处	://WOS:000307259400033
公开日期	2013-02-05
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/59946]
专题	金属研究所_中国科学院金属研究所
推荐引用方式 GB/T 7714	W. L. Feng,M. F. Zhao,T. Li,et al. Theoretical Studies of ESR Parameters and Local Lattice Structure of the Vanadate-Lithium-Borate Glasses[J]. Acta Physica Polonica A,2012,122(1):167-169.
APA	W. L. Feng,M. F. Zhao,T. Li,X. H. Zhang,&J. Y. Xue.(2012).Theoretical Studies of ESR Parameters and Local Lattice Structure of the Vanadate-Lithium-Borate Glasses.Acta Physica Polonica A,122(1),167-169.
MLA	W. L. Feng,et al."Theoretical Studies of ESR Parameters and Local Lattice Structure of the Vanadate-Lithium-Borate Glasses".Acta Physica Polonica A 122.1(2012):167-169.