Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate

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	Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate
	W. L. Feng
刊名	Philosophical Magazine Letters
	2012
卷号	92 期号:8 页码:368-372
关键词	crystal-field theory Raman spectra ESR (C(NH2)(3)V(SO4)(2)center dot 6H(2)O V3+ spin-hamiltonian parameters epr g-factors optical-spectra single-crystals spectroscopy cation
ISSN号	0950-0839
中文摘要	The Raman spectra and electronic spin resonance (ESR) parameters (spin-Hamiltonian parameter g factors, zero-field splitting parameter D, and hyperfine structure constant A) for the trigonal V3+ centers in salt guanidinium vanadium sulfate hexahydrate (GVSH) are calculated from the complete diagonalization (of energy matrix) method. The theoretical results are in agreement with the experimental findings and the trigonal crystal-field parameters are determined. The difficulty in explaining ESR parameters of V3+ in GVSH is removed.
原文出处	://WOS:000306288200003
公开日期	2013-02-05
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/59943]
专题	金属研究所_中国科学院金属研究所
推荐引用方式 GB/T 7714	W. L. Feng. Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate[J]. Philosophical Magazine Letters,2012,92(8):368-372.
APA	W. L. Feng.(2012).Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate.Philosophical Magazine Letters,92(8),368-372.
MLA	W. L. Feng."Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate".Philosophical Magazine Letters 92.8(2012):368-372.