Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate | |
W. L. Feng | |
刊名 | Philosophical Magazine Letters
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2012 | |
卷号 | 92期号:8页码:368-372 |
关键词 | crystal-field theory Raman spectra ESR (C(NH2)(3)V(SO4)(2)center dot 6H(2)O V3+ spin-hamiltonian parameters epr g-factors optical-spectra single-crystals spectroscopy cation |
ISSN号 | 0950-0839 |
中文摘要 | The Raman spectra and electronic spin resonance (ESR) parameters (spin-Hamiltonian parameter g factors, zero-field splitting parameter D, and hyperfine structure constant A) for the trigonal V3+ centers in salt guanidinium vanadium sulfate hexahydrate (GVSH) are calculated from the complete diagonalization (of energy matrix) method. The theoretical results are in agreement with the experimental findings and the trigonal crystal-field parameters are determined. The difficulty in explaining ESR parameters of V3+ in GVSH is removed. |
原文出处 | |
公开日期 | 2013-02-05 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/59943] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. L. Feng. Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate[J]. Philosophical Magazine Letters,2012,92(8):368-372. |
APA | W. L. Feng.(2012).Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate.Philosophical Magazine Letters,92(8),368-372. |
MLA | W. L. Feng."Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate".Philosophical Magazine Letters 92.8(2012):368-372. |
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