Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant

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	Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant
	Xu SM(徐森苗) ; Wang Z(王正) ; Zhang XM(张绪穆) ; Ding KL(丁奎岭)
刊名	Chin. J. Chem.
	2010
卷号	28 期号:9 页码:1731-1735
ISSN号	1001-604X
其他题名	手性磷酸催化的不对称BV氧化反应中的电荷转移效应
通讯作者	丁奎岭
英文摘要	The intermolecular charge-transfer effect has been employed for the first time as a modulating approach to affect the enantioselectivity in asymmetric catalysis by taking the chiral phosphoric acid catalyzed asymmetric Baeyer-Villiger oxidation of 3-aryl cyclobutanones as the reaction prototype. It was found that the electron acceptor additives were able to effectively tune the enantioselectivity via donor-acceptor interaction with the catalyst and up to 9% enhancement of ee value was observed in a favorable case.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/cjoc.201090292
语种	英语
WOS记录号	WOS:000282998700035
公开日期	2013-02-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/17867]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Xu SM,Wang Z,Zhang XM,et al. Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant[J]. Chin. J. Chem.,2010,28(9):1731-1735.
APA	徐森苗,王正,张绪穆,&丁奎岭.(2010).Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant.Chin. J. Chem.,28(9),1731-1735.
MLA	徐森苗,et al."Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant".Chin. J. Chem. 28.9(2010):1731-1735.