Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant | |
Xu SM(徐森苗) ; Wang Z(王正) ; Zhang XM(张绪穆) ; Ding KL(丁奎岭) | |
刊名 | Chin. J. Chem.
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2010 | |
卷号 | 28期号:9页码:1731-1735 |
ISSN号 | 1001-604X |
其他题名 | 手性磷酸催化的不对称BV氧化反应中的电荷转移效应 |
通讯作者 | 丁奎岭 |
英文摘要 | The intermolecular charge-transfer effect has been employed for the first time as a modulating approach to affect the enantioselectivity in asymmetric catalysis by taking the chiral phosphoric acid catalyzed asymmetric Baeyer-Villiger oxidation of 3-aryl cyclobutanones as the reaction prototype. It was found that the electron acceptor additives were able to effectively tune the enantioselectivity via donor-acceptor interaction with the catalyst and up to 9% enhancement of ee value was observed in a favorable case. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/cjoc.201090292 |
语种 | 英语 |
WOS记录号 | WOS:000282998700035 |
公开日期 | 2013-02-22 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/17867] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Xu SM,Wang Z,Zhang XM,et al. Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant[J]. Chin. J. Chem.,2010,28(9):1731-1735. |
APA | 徐森苗,王正,张绪穆,&丁奎岭.(2010).Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant.Chin. J. Chem.,28(9),1731-1735. |
MLA | 徐森苗,et al."Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant".Chin. J. Chem. 28.9(2010):1731-1735. |
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