Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates

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	Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates
	Chen JP(陈建平) ; Ding CH(丁昌华) ; Liu W(刘卫) ; Hou XL(侯雪龙) ; Dai LX(戴立信)
刊名	J. Am. Chem. Soc.
	2010
卷号	132 期号:44 页码:15493-15495
ISSN号	0002-7863
其他题名	钯催化开链酰基硅和单取代烯丙基底物的区域非对映、对映选择性烯丙基烷基化反应
通讯作者	侯雪龙
英文摘要	Acylsilanes as a new type of "hard" carbon prenucleo-phile reacted with monosubstituted allyl reagents under Pd-catalyzed asymmetric allylic alkylation reaction conditions to provide products with high regio-, diastereo-, and enantioselectivities. The usefulness of the protocol has been demonstrated by the ready conversion of the allylated products into the corresponding alcohols, esters, and ketones with retention of stereochemistry as well as by the enantioselective synthesis of cis-3-ethyl-4-phenylpiperidine and cinnamomumolide.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ja106703y
语种	英语
WOS记录号	WOS:000283955600012
公开日期	2013-02-19
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/15993]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Chen JP,Ding CH,Liu W,et al. Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates[J]. J. Am. Chem. Soc.,2010,132(44):15493-15495.
APA	陈建平,丁昌华,刘卫,侯雪龙,&戴立信.(2010).Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates.J. Am. Chem. Soc.,132(44),15493-15495.
MLA	陈建平,et al."Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates".J. Am. Chem. Soc. 132.44(2010):15493-15495.