Co-ordinatively unsaturated neodymium hydrides, stability in solution

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	Co-ordinatively unsaturated neodymium hydrides, stability in solution
	Marc Visseaux ; Denise Baudry ; Alain Dormond ; Qian ZT(钱长涛)
刊名	J. Organomet. Chem.
	1999
卷号	574 页码:213-218
ISSN号	0022-328X
其他题名	配位不饱和的钕的氢化物，溶液中的稳定性
通讯作者	Marc Visseaux
英文摘要	The tris-alkyborohydride Cp^~Q NdHBEt^3 (Cp^Q=C^5H^4CH^2CH^2OCH^3) obtained by reaction of NaHBEt^3 with CP^2~QNdCl is fairly stable in solution whereas the hydride CP^2~Q NdH formed from Cp^2~QNdCl and NAH or by hydrogenolsis of Cp^2~Q NDR (R=CH^2SiMe^3 or CH(SiMe^3)^2) is a species of very short life, undergoing rearrangement to Cp^3QNd. This transient hydride is not observed but can be trapped with ketones-propanone or pivalone. Leading to the alkoxides Cp^2~QNdOCHR^2(R'=Me or CM^3). The same alkoxides are obtained from Cp^2~QNdHBEt^3.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/S0022-328X(98)00549-X
语种	英语
WOS记录号	WOS:000079056500002
公开日期	2013-01-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/15219]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Marc Visseaux,Denise Baudry,Alain Dormond,et al. Co-ordinatively unsaturated neodymium hydrides, stability in solution[J]. J. Organomet. Chem.,1999,574:213-218.
APA	Marc Visseaux,Denise Baudry,Alain Dormond,&钱长涛.(1999).Co-ordinatively unsaturated neodymium hydrides, stability in solution.J. Organomet. Chem.,574,213-218.
MLA	Marc Visseaux,et al."Co-ordinatively unsaturated neodymium hydrides, stability in solution".J. Organomet. Chem. 574(1999):213-218.