Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis

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	Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis
	Zhang QH(张庆海) ; Xu Y(许蔚) ; Lu XY(陆熙炎)
刊名	J. Org. Chem.
	2005
卷号	70 期号:4 页码:1505-1507
ISSN号	0022-3263
其他题名	钯(II)催化的以乙酸基为亲核试剂的1,6-烯炔的环异构化
通讯作者	陆熙炎
英文摘要	An efficient method for the synthesis of five-membered carbo- and heterocyclic compounds, including fused rings, was reported using acetate as a nucleophile in the cyclization of 1,6-enynes under palladium(II) catalysis. The reaction is initiated by trans-acetoxypalladation of the alkynes and quenched by either trans- or cis-deacetoxypalladation in the presence of 2,2'-bipyridine as the ligand. An example of the catalytic asymmetric cyclization is presented with moderate enantioselectivity using chiral bisoxazoline ligand.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo048414o
语种	英语
WOS记录号	WOS:000227075600056
公开日期	2013-01-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14834]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Zhang QH,Xu Y,Lu XY. Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis[J]. J. Org. Chem.,2005,70(4):1505-1507.
APA	张庆海,许蔚,&陆熙炎.(2005).Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis.J. Org. Chem.,70(4),1505-1507.
MLA	张庆海,et al."Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis".J. Org. Chem. 70.4(2005):1505-1507.