Palladium(II)-catalyzed tandem reaction of intramolecular aminopalladation of allenyl N-tosylcarbamates and conjugate addition

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	Palladium(II)-catalyzed tandem reaction of intramolecular aminopalladation of allenyl N-tosylcarbamates and conjugate addition
	Liu GS(刘国生) ; Lu XY(陆熙炎)
刊名	Org. Lett.
	2001
卷号	3 期号:24 页码:3879-3882
ISSN号	1523-7060
其他题名	二价钯催化下N-对甲苯磺酰基胺基甲算联烯酯分子内胺钯化和共轭加成的串联反应
通讯作者	陆熙炎
英文摘要	A divalent palladium-catalyzed tandem cyclization-coupling reaction of allenyl N-tosylcarbamates and acrolein was developed. The reaction gave aldehyde-functionalized 2-oxazolidinones in one step with high regioselectivity. A mechanism involving intramolecular aminopalladation of allene, followed by insertion of alkene and C-Pd bond protonlysis, is proposed.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol016727p
语种	英语
WOS记录号	WOS:000172418200016
公开日期	2013-01-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14782]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Liu GS,Lu XY. Palladium(II)-catalyzed tandem reaction of intramolecular aminopalladation of allenyl N-tosylcarbamates and conjugate addition[J]. Org. Lett.,2001,3(24):3879-3882.
APA	刘国生,&陆熙炎.(2001).Palladium(II)-catalyzed tandem reaction of intramolecular aminopalladation of allenyl N-tosylcarbamates and conjugate addition.Org. Lett.,3(24),3879-3882.
MLA	刘国生,et al."Palladium(II)-catalyzed tandem reaction of intramolecular aminopalladation of allenyl N-tosylcarbamates and conjugate addition".Org. Lett. 3.24(2001):3879-3882.