Palladium-Catalyzed Regioselective Cyclopropanating Allenylation of (2,3-Butadienyl)malonates with Propargylic Carbonates and Their Application to Synthesize Cyclopentenones

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	Palladium-Catalyzed Regioselective Cyclopropanating Allenylation of (2,3-Butadienyl)malonates with Propargylic Carbonates and Their Application to Synthesize Cyclopentenones
	Shu W(舒伟) ; Jia GC(贾国成) ; Ma SM(麻生明)
刊名	Org. Lett.
	2009
卷号	11 期号:1 页码:117-120
ISSN号	1523-7060
其他题名	钯催化的2,3-丁二烯取代的丙二酸酯和丙炔碳酸酸的区域选择的环丙烷化联烯基化反应及其在合成环戊烯酮中的应用
通讯作者	麻生明
英文摘要	An efficient and highly regioselective route to synthesize polysubstituted 1,3,4-alkatrien-2-yl cyclopropane derivatives via Pd(0)-catalyzed highly regioselective coupling cyclization of (2,3-butadienyl)malonate or bis(phenylsulfonyl)methane with propargylic carbonates was reported. The reaction proceeded smoothly under neutral conditions to afford the products in 73-96% yields. The products may be efficiently converted to cyclopentenone derivatives via a catalytic Pauson-Khand reaction under ambient conditions.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol802465k
语种	英语
WOS记录号	WOS:000262018700030
公开日期	2013-01-16
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/12208]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Shu W,Jia GC,Ma SM. Palladium-Catalyzed Regioselective Cyclopropanating Allenylation of (2,3-Butadienyl)malonates with Propargylic Carbonates and Their Application to Synthesize Cyclopentenones[J]. Org. Lett.,2009,11(1):117-120.
APA	舒伟,贾国成,&麻生明.(2009).Palladium-Catalyzed Regioselective Cyclopropanating Allenylation of (2,3-Butadienyl)malonates with Propargylic Carbonates and Their Application to Synthesize Cyclopentenones.Org. Lett.,11(1),117-120.
MLA	舒伟,et al."Palladium-Catalyzed Regioselective Cyclopropanating Allenylation of (2,3-Butadienyl)malonates with Propargylic Carbonates and Their Application to Synthesize Cyclopentenones".Org. Lett. 11.1(2009):117-120.