Studies on electrophilic interaction of 2,3-allenols with electrophilic halogen reagents: Selective synthesis of 2,5-dihydrofurans, 3-halo-3-alkenals, or 2-halo-2-alkenyl ketones

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	Studies on electrophilic interaction of 2,3-allenols with electrophilic halogen reagents: Selective synthesis of 2,5-dihydrofurans, 3-halo-3-alkenals, or 2-halo-2-alkenyl ketones
	Li J(李晶) ; Fu CL(傅春玲) ; Chen GF(陈国飞) ; Chai GB(柴国碧) ; Ma SM(麻生明)
刊名	Adv. Synth. Catal.
	2008
卷号	350 期号:9 页码:1376-1382
ISSN号	1615-4150
其他题名	Studies on electrophilic interaction of 2,3-allenols with electrophilic halogen reagents: Selective synthesis of 2,5-dihydrofurans, 3-halo-3-alkenals, or 2-halo-2-alkenyl ketones
通讯作者	麻生明
英文摘要	The reaction of primary 2,3-allenols with iodine (I-2) afforded 2,5-dihydrofurans while that of readily available 1-aryl or 1-methyl substituted 2,3-allenols with bromine (Br-2), N-bromosuccinimide (NBS), I-2 or N-iodosuccinimide (NIS) formed the not easily available but synthetically useful 3-halo-3-alkenals and 2-halo-2-alkenyl ketones with good selectivity and yields via a sequential electrophilic interaction of X+ with the allene moiety, 1,2-aryl or 1,2-proton shift, and H+ elimination process.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/adsc.200800088
语种	英语
WOS记录号	WOS:000256976100030
公开日期	2013-01-16
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/12164]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Li J,Fu CL,Chen GF,et al. Studies on electrophilic interaction of 2,3-allenols with electrophilic halogen reagents: Selective synthesis of 2,5-dihydrofurans, 3-halo-3-alkenals, or 2-halo-2-alkenyl ketones[J]. Adv. Synth. Catal.,2008,350(9):1376-1382.
APA	李晶,傅春玲,陈国飞,柴国碧,&麻生明.(2008).Studies on electrophilic interaction of 2,3-allenols with electrophilic halogen reagents: Selective synthesis of 2,5-dihydrofurans, 3-halo-3-alkenals, or 2-halo-2-alkenyl ketones.Adv. Synth. Catal.,350(9),1376-1382.
MLA	李晶,et al."Studies on electrophilic interaction of 2,3-allenols with electrophilic halogen reagents: Selective synthesis of 2,5-dihydrofurans, 3-halo-3-alkenals, or 2-halo-2-alkenyl ketones".Adv. Synth. Catal. 350.9(2008):1376-1382.