Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis

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	Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis
	Liu LJ(刘连军) ; Wang FJ(王飞军) ; Shi M(施敏)
刊名	Organometallics
	2009
卷号	28 期号:15 页码:4416-4420
ISSN号	0276-7333
其他题名	具有联苯骨架的手性氮杂环卡宾配体的合成及其在不对称催化反应中的应用
英文摘要	Axially chiral bis(NFIC) Pd(II) and Rh(III) complexes with 1,1'-biphenyl scaffold have been successfully synthesized from the corresponding chiral 6,6'-dimethoxybiphenyl-2-2'-diamine. These interesting NFIC-metal complexes have been characterized by X-ray crystal structure diffraction. When applied in the oxidative kinetic resolution of sec-alcohols and hydrosilylation of ketones, these catalysts showed good catalytic activities with moderate to high enantioselectivities.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om900320c
语种	英语
WOS记录号	WOS:000268455900027
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10270]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Liu LJ,Wang FJ,Shi M. Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis[J]. Organometallics,2009,28(15):4416-4420.
APA	刘连军,王飞军,&施敏.(2009).Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis.Organometallics,28(15),4416-4420.
MLA	刘连军,et al."Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis".Organometallics 28.15(2009):4416-4420.