The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters
	Xu Q(徐琴) ; Gu XX(顾星星) ; Liu SJ(刘思佳) ; Dou QY(窦清玉) ; Shi M(施敏)
刊名	J. Org. Chem.
	2007
卷号	72 期号:6 页码:2240-2242
ISSN号	0022-3263
其他题名	手性氮杂卡宾配体和金属铑配和物在?-酮酸酯的不对称还原中的应用
英文摘要	Axially chiral BINAM N-heterocyclic carbene (NHC)-Rh-(III) complexes were applied in the enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters. The reduction products 3-hydroxy-3-arylpropionic acid methyl or ethyl esters could be obtained in good yields with good to excellent enantioselectivities under mild conditions.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo062453d
语种	英语
WOS记录号	WOS:000244773600047
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10110]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Xu Q,Gu XX,Liu SJ,et al. The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters[J]. J. Org. Chem.,2007,72(6):2240-2242.
APA	徐琴,顾星星,刘思佳,窦清玉,&施敏.(2007).The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters.J. Org. Chem.,72(6),2240-2242.
MLA	徐琴,et al."The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters".J. Org. Chem. 72.6(2007):2240-2242.