Hydroamination of olefin in a special conjugated spiroketal enol ether system, diastereoselective synthesis of amino-containing tonghaosu analogs | |
Yin BL(尹标林) ; Hu TS(胡泰山) ; Wu YL(吴毓林) | |
刊名 | Tetrahedron Lett.
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2004 | |
卷号 | 45期号:9页码:2017-2021 |
ISSN号 | 0040-4039 |
其他题名 | 共轭螺环烯醇醚的双键的氢胺化反应:立体选择性合成含氨基的茼蒿素类似物 |
通讯作者 | 吴毓林 |
英文摘要 | Lithium amide reacted with spiroketal enol ether characterized tonghaosu analog at -78degreesC to give the only hydroamination product 4 in a highly regio- and diastereoselective manner. At a higher temperature, -40degreesC, the presence of free amine was critical for the hydroamination to take place; otherwise, rearrangement of tonghaosu analog to 2,3-dihydrofuran derivative like 6 was the only reaction. (C) 2004 Published by Elsevier Ltd. |
学科主题 | 生命有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tetlet.2003.11.106 |
语种 | 英语 |
WOS记录号 | WOS:000189116200047 |
公开日期 | 2013-01-17 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/14086] ![]() |
专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Yin BL,Hu TS,Wu YL. Hydroamination of olefin in a special conjugated spiroketal enol ether system, diastereoselective synthesis of amino-containing tonghaosu analogs[J]. Tetrahedron Lett.,2004,45(9):2017-2021. |
APA | 尹标林,胡泰山,&吴毓林.(2004).Hydroamination of olefin in a special conjugated spiroketal enol ether system, diastereoselective synthesis of amino-containing tonghaosu analogs.Tetrahedron Lett.,45(9),2017-2021. |
MLA | 尹标林,et al."Hydroamination of olefin in a special conjugated spiroketal enol ether system, diastereoselective synthesis of amino-containing tonghaosu analogs".Tetrahedron Lett. 45.9(2004):2017-2021. |
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