Hydrogen bonding-mediated oligobenzamide foldamer receptors that efficiently bind a triol and saccharides in chloroform

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 物理有机化学研究室

	Hydrogen bonding-mediated oligobenzamide foldamer receptors that efficiently bind a triol and saccharides in chloroform
	Yi HP(易会萍) ; Shao XB(邵学斌) ; Hou JL(侯军利) ; Li C(李闯) ; Jiang XK(蒋锡夔) ; Li ZT(黎占亭)
刊名	New J. Chem.
	2005
卷号	29 期号:9 页码:1213-1218
ISSN号	1144-0546
其他题名	氢键介质的寡聚苯甲酰胺折叠体在氯仿中高效结合三醇及糖衍生物
通讯作者	黎占亭
英文摘要	The self- assembly of two novel intramolecular hydrogen bonding- driven foldamers is described. Two linear symmetric aromatic amide oligomers, 1 and 2, which are incorporated with benzene subunits, have been prepared by continuous amide- coupling reactions. The existence of three- centred hydrogen bonds in the oligomers and consequently the folding conformation of the oligomers in solution have been characterized by H-1 NMR experiments and by comparing them with the reported solid state structure of the identical structural skeleton. Molecular modeling reveals a rigid crescent conformation for 1 with a cavity of ca. 0.9 nm in diameter and a helical conformation for 2 with a cavity of ca. 0.8 nm in diameter. Due to the existence of intramolecular hydrogen bonding, all the C = O groups in both oligomers are located inwardly. The binding of 1 and 2 towards a trihydroxyl guest and four saccharide derivatives have been investigated with H-1 NMR, fluorescence, and circular dichroism spectroscopy. The association constants of the corresponding 1 : 1 complexes have been determined by fluorescence titration experiments.
学科主题	物理有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/b508773b
语种	英语
WOS记录号	WOS:000231364500019
公开日期	2013-01-16
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/12676]
专题	上海有机化学研究所_物理有机化学研究室
推荐引用方式 GB/T 7714	Yi HP,Shao XB,Hou JL,et al. Hydrogen bonding-mediated oligobenzamide foldamer receptors that efficiently bind a triol and saccharides in chloroform[J]. New J. Chem.,2005,29(9):1213-1218.
APA	易会萍,邵学斌,侯军利,李闯,蒋锡夔,&黎占亭.(2005).Hydrogen bonding-mediated oligobenzamide foldamer receptors that efficiently bind a triol and saccharides in chloroform.New J. Chem.,29(9),1213-1218.
MLA	易会萍,et al."Hydrogen bonding-mediated oligobenzamide foldamer receptors that efficiently bind a triol and saccharides in chloroform".New J. Chem. 29.9(2005):1213-1218.