Synthesis of gem-difluoromethylenated analogues of boronolide | |
Lin J(林静) ; Qiu XL(邱小龙) ; Qing FL(卿凤翎) | |
刊名 | Beilstein J. Org. Chem. |
2010 | |
卷号 | 6页码:37 |
ISSN号 | 1860-5397 |
其他题名 | Synthesis of gem-difluoromethylenated analogues of boronolide |
通讯作者 | 卿凤翎 |
英文摘要 | The straightforward synthesis of four gem-difluoromethylenated analogues 4-7 of boronolide is described. The key steps of the synthesis include the concise preparation of the key intermediates 12a-b through the indium-mediated gem-difluoropropargylation of aldehyde 9 with the fluorine-containing building block 11 and the efficient construction of alpha,beta-unsaturated-delta-lactones 15a-b via BAIB/TEMPO-procedure. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.3762/bjoc.6.37 |
语种 | 英语 |
WOS记录号 | WOS:000277432500001 |
公开日期 | 2013-02-22 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/17679] |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | Lin J,Qiu XL,Qing FL. Synthesis of gem-difluoromethylenated analogues of boronolide[J]. Beilstein J. Org. Chem.,2010,6:37. |
APA | 林静,邱小龙,&卿凤翎.(2010).Synthesis of gem-difluoromethylenated analogues of boronolide.Beilstein J. Org. Chem.,6,37. |
MLA | 林静,et al."Synthesis of gem-difluoromethylenated analogues of boronolide".Beilstein J. Org. Chem. 6(2010):37. |
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